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Which of the following is expected to be...

Which of the following is expected to be a paramagnetic complex?

A

`[Ni(H_(2)O)_(6)]^(2+)`

B

`[NI(CO)_(4)]`

C

`[Zn(NH_(3))_(4)]^(2+)`

D

`[Co(NH_(3))_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
A

In the complex the outer electronic configuration of Ni(II) is `d^(8)` . It has two unpaired electrons which cannot pair up in the presence of `H_(2)O` molecules which are weak ligands . The complex is paramagnetic in nature.
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Select the correct answers
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  7. Which of the following will give maximum number of isomer ?

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  18. What is the number of possible isomers for the octahedral complex [Co(...

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