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[Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a...

`[Cr(H_2 O)_6]Cl_3` (at no. of Cr = 24) has a magnetic moment of `3.83 B.M`. The correct distribution of `3d` electrons the chromium of the complex.

A

`3d_(xy)^(1) , 3d_(yz)^(1) , 3d_(xz)^(1)`

B

`3d_(xy)^(1) , 3d_(yz)^(1) , 3d_(z^(2))^(1)`

C

`3d_(x^(2) - y^(2))^(1) , 3d_(z^(2))^(1) , 3d_(xz)^(1)`

D

`3d_(xy)^(1) , 3dx^(2) - y^(2) , 3d_(yz)^(1)`

Text Solution

Verified by Experts

The correct Answer is:
A

a) Since the magnetic moment`(mu)` = 3.83 BM, the numbe of unpaired ios 3.
`sqrt(n(n+2)) = 3.83` or `n(n+2) = (3.83)^(2) = 15`
this means that n=3
`d^(2)sp^(3)` hybridisation
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