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The complex with maximum magnetic in the...

The complex with maximum magnetic in the following is :

A

`[CoF_(6)]^(3-)`

B

`[Co(NH_(3))_(6)]^(3+)`

C

`[Ni(NH_(3))_(4)]^(2+)`

D

`[Ni(CN)_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Since `F^(-)` ions are weak field lifands, they cannot cause any electron pairing `(Co^(3+)` ) ion is the complex has `3d^(8)` configuration with four unpaired electrons. The complex is expected to be maximum paramagnetic in nature. All other complexes are of diamagnetic nature since the liagads are strong ligands.
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Select the correct answers
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  6. d^(2)sp(3) hybridisation of the atomic orbital gives :

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  7. Which one of the following forms with an excess of CN^(-) (Cyanide) a ...

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  8. Which of the following has a regular tetrahedral structure ?

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  11. Which of the following complexes has lowest molar conductance ?

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  12. The colour of the co-ordination compounds is explained in terms of :

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  13. In which of the pairs of ions given, there is an ion that forms a co-o...

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  20. Which one of the following complexes shows optical isomerism ?

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