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PbCl(2) is insoluble in cold water. Addi...

`PbCl_(2)` is insoluble in cold water. Addition of HCl increases its solubility due to

A

formation of soluble complex anions like ``

B

oxidation of Pb(II) to Pb(IV)

C

formation of ``

D

formation of polymeric lead complexes .

Text Solution

Verified by Experts

The correct Answer is:
A

Addition of `Cl^(-)` ions to a of suspension `PbCl_2` gives rise to soluble complex ions :
`PbCl_2`(s) + `Cl^(-)`(aq) `` `[PbCl_3]^(-)`(aq)
`PbCl_2`(s) + `2Cl^(-)`(aq) `` `[PbCl_4]^(2-)`(aq) .
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