Home
Class 12
CHEMISTRY
When the valence d-orbitals of the centr...

When the valence d-orbitals of the central metal ion split in energy in an octahedral ligand field, which orbitals are raised least in energy ?

A

`d_(x^(2)-y^(2))`

B

`d_(xz)`

C

`d_(yz)`

D

`d_(z)^(2)`

Text Solution

Verified by Experts

The correct Answer is:
b,c

(b,c) are correct answers
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Assertion-Reason type question|21 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise INTEGER ANSWER TYPE QUESTIONS|18 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Straight objective type mcqs|17 Videos
  • CHEMISTRY IN EVERY DAY LIFE

    DINESH PUBLICATION|Exercise Unit test-9|50 Videos
  • CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES

    DINESH PUBLICATION|Exercise Unit test - 8|20 Videos

Similar Questions

Explore conceptually related problems

4s orbitals has less energy than 3d orbital

Draw figure to show the splitting of d orbitals in an octahedral crystal field.

In crystal field splitting for a tetrahedral complex, the number of orbitals pushed down in energy are

Which ion produces a small crystal field splitting (a weak ligand field)?

According to cystal field theory, interaction between central metal atom/ion and ligand is electrostatic in nature. In free metal ions, the five d-orbitals are degenerate. However, in a ligand field e.g., tetrahedral, octahedral, square planar, square pyramidal, trigonal bipyramidal, the degeneracy of 5d-orbitals is lost. If lobes of d-orbitals of central metal atom/ion are along the axes through which ligands are approaching, the energy of corresponding d-orbital is raised more than the d-orbitals having lobes between teh axes. e.g., octahedral complexes, square planar complexes, square pyramidal compexes. Which of the following orbitals has the highest energy in square pyramidal ligand field ?