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The pair of coordination complex exhibit...

The pair of coordination complex exhibiting the same kind of isomerism is .

A

`[Cr(NH_(3))_(5)Cl]Cl_(2)` and `[Cr(NH_(3))_(4)Cl_(2)]Cl`

B

`[Co(NH_(3))_(4)Cl_(2)]^(2+)` and `[Pt(NH_(3))_(2)(H_(2)O)Cl]^(+)`

C

`[CoBr_(2)Cl_(2)]^(2-)` and `[PtBr_(2)Cl_(2)]^(2-)`

D

`[Pt(NH_(3))_(3)(NO_(3))]Cl` and `[Pt(NH_(3))_(3)Cl]Br`

Text Solution

Verified by Experts

The correct Answer is:
b,d
(b,d) The complex `[Co(NH_3)_4Cl_2]^(+)` and `[Pt(NH_3)_2(H_(2)O)Cl^(-)` both exhibit geometrical isomerism (b) .
The complex `[Pt(NH_3)_3(NO_3)CL] ` and `[Pt(NH_3)Cl]Br` both exhibit ionisation isomerism (d) .
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