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Statement (A) Carboxylic acid can be obt...

Statement (A) Carboxylic acid can be obtained by the reaction of `R-C-=N` with `H_(3)overset(o+)"O"` under mild reaction conditions.
Statement (B) Hydrolysis of `R-C-=N` in alkaline aqueous medium gives `R-"CO"overset(Θ )"O"overset(o+)Na` and `overset(●●)"N""H"_(3)` as products.

A

Both (A) and (B) are correct

B

Both (A) and (B) are not correct

C

(A) is correct, but (B) is not correct

D

(A) is not correct but (B) is correct

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The correct Answer is:
D

Carboxylic acid can be obtained by complete hydrolysis of `R-CN`. Therefore, statement (A) is incorrect.

When alkyl cyanide hydrolysed in presence of alkaline medium, `R-CO overset(-)Ooverset(+)Na-Na` and ammonia gas are obtained
`R-C-=N underset(NaOH)overset(H_(2)O //H^(+))rarr R-underset("O")underset("||")C-overset(-)Ooverset(+)Na+NH_(3)`
Therefore, statement (B) is correct.
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