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The root-mean-square (rms) speed of oxyg...

The root-mean-square (rms) speed of oxygen molecules `(O_(2))` at a certain absolute temperature is v.If the temperature is double and the oxygen gas dissociated into atomic oxygen, the rms speed would be

A

v

B

`sqrt2 v`

C

2 v

D

`2sqrt2 v`

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The correct Answer is:
To solve the problem, we need to understand the relationship between the root-mean-square (rms) speed of gas molecules, temperature, and mass. The formula for the rms speed \( v_{rms} \) is given by: \[ v_{rms} = \sqrt{\frac{3kT}{m}} \] where: - \( k \) is the Boltzmann constant, - \( T \) is the absolute temperature, - \( m \) is the mass of a single molecule of the gas. ### Step 1: Identify the initial conditions The initial rms speed of oxygen molecules \( O_2 \) at a certain temperature \( T \) is given as \( v \). The molar mass of \( O_2 \) is 32 g/mol, which means the mass of a single \( O_2 \) molecule is: \[ m_{O_2} = \frac{32 \, \text{g/mol}}{N_A} \quad \text{(where \( N_A \) is Avogadro's number)} \] ### Step 2: Determine the new conditions after doubling the temperature and dissociating the gas When the temperature is doubled, the new temperature \( T' \) becomes: \[ T' = 2T \] When \( O_2 \) dissociates into atomic oxygen, the mass of a single oxygen atom \( O \) becomes: \[ m_O = \frac{16 \, \text{g/mol}}{N_A} \] ### Step 3: Calculate the new rms speed Using the rms speed formula for atomic oxygen at the new temperature: \[ v'_{rms} = \sqrt{\frac{3kT'}{m_O}} = \sqrt{\frac{3k(2T)}{m_O}} \] Substituting \( m_O \) into the equation: \[ v'_{rms} = \sqrt{\frac{3k(2T)}{m_O}} = \sqrt{\frac{3k(2T)}{\frac{16 \, \text{g/mol}}{N_A}}} \] ### Step 4: Relate the new rms speed to the initial rms speed Now we can relate the new rms speed \( v'_{rms} \) to the initial rms speed \( v_{rms} \): 1. The initial rms speed for \( O_2 \) is: \[ v_{rms} = \sqrt{\frac{3kT}{m_{O_2}}} = \sqrt{\frac{3kT}{\frac{32 \, \text{g/mol}}{N_A}}} \] 2. The new rms speed becomes: \[ v'_{rms} = \sqrt{\frac{3k(2T)}{\frac{16 \, \text{g/mol}}{N_A}}} \] 3. Simplifying the ratio of the new rms speed to the initial rms speed: \[ \frac{v'_{rms}}{v_{rms}} = \sqrt{\frac{2T \cdot \frac{32}{N_A}}{T \cdot \frac{16}{N_A}}} = \sqrt{\frac{2 \cdot 32}{16}} = \sqrt{4} = 2 \] ### Conclusion Thus, the new rms speed \( v'_{rms} \) is: \[ v'_{rms} = 2v \] So, the final answer is that the rms speed would be \( 2v \).

To solve the problem, we need to understand the relationship between the root-mean-square (rms) speed of gas molecules, temperature, and mass. The formula for the rms speed \( v_{rms} \) is given by: \[ v_{rms} = \sqrt{\frac{3kT}{m}} \] where: - \( k \) is the Boltzmann constant, ...
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DC PANDEY-THERMOMETRY THERMAL EXPANSION AND KINETIC THEORY OF GASES-Check point 14.3
  1. Which one of the following is not an assumption in the kinetic theory ...

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  2. A closed vessel is maintained at a constant temperture. It is first ev...

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  3. The average speedof lulecules in a gas is given by

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  4. For gas at a temperature T the root-mean-square speed v(rms), the most...

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  5. The average kinetic enrergy of a gas molecule is

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  6. KE per unit volume is E. The pressure exerted by the gas is given by

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  7. If at the same temperature and pressure, the densities of two diatomic...

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  8. Two vessels A and B having equal volume contain equal masses of hydrog...

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  9. A vessel contains 1 mole of O(2) gas (molar mass 32) at a temperature ...

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  10. What will be the temperature when the rms velocity is double of that a...

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  11. By what factor the rms velocity will change, if the temperature s rais...

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  12. The velocities of three molecules are 3v, 4v and 5v. Calculate their r...

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  13. The temperature at which the root mean squres speed of a gas will be h...

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  14. Four molecules of ags have speeds 1,2,3 and 4 km//s.The volue of the r...

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  15. A sealed container with negiligible coefficient of volumetric expansio...

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  16. The gases carbon-monoxide (CO) and nitrogen at the same temperature ha...

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  17. Pressure of an ideal gas is increased by keeping temperature constant....

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  18. Some gas at 300K is enclosed in a container. Now the container is plac...

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  19. The root-mean-square (rms) speed of oxygen molecules (O(2)) at a certa...

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  20. The molecules of a given mass of a gas have rms velocity of 200 m//s a...

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