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The energies of three consecutive energy...

The energies of three consecutive energy levels `L_(3), L_(2) and L_(1)` of hydrogen atom are `E_(0), 4E_(0)/9` and `E_(0)/4` respectively. A photon of wavelength `lambda` is emitted for a transition `L_(3) to L_(1)` . What will be the wavelength of emission for transition `L_(2) to L_(1)`?

A

`16lambda/31`

B

`27lambda/7`

C

`19/20 lambda`

D

`lambda`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the wavelength of emission for the transition from energy level \(L_2\) to \(L_1\) in a hydrogen atom, given the energies of the three consecutive energy levels \(L_3\), \(L_2\), and \(L_1\). ### Step-by-Step Solution: 1. **Identify the Energy Levels**: - Given: - \(E_{L_3} = E_0\) - \(E_{L_2} = \frac{4E_0}{9}\) - \(E_{L_1} = \frac{E_0}{4}\) 2. **Calculate the Energy Change for Transition \(L_3 \to L_1\)**: - The energy change (\(\Delta E_{31}\)) for the transition from \(L_3\) to \(L_1\) is: \[ \Delta E_{31} = E_{L_3} - E_{L_1} = E_0 - \frac{E_0}{4} = \frac{3E_0}{4} \] 3. **Relate Energy Change to Wavelength**: - According to Planck's law, the energy of a photon is given by: \[ E = \frac{hc}{\lambda} \] - Setting the energy change equal to the energy of the emitted photon: \[ \frac{3E_0}{4} = \frac{hc}{\lambda} \] - Rearranging gives us: \[ \lambda = \frac{hc}{\frac{3E_0}{4}} = \frac{4hc}{3E_0} \] 4. **Calculate the Energy Change for Transition \(L_2 \to L_1\)**: - The energy change (\(\Delta E_{21}\)) for the transition from \(L_2\) to \(L_1\) is: \[ \Delta E_{21} = E_{L_2} - E_{L_1} = \frac{4E_0}{9} - \frac{E_0}{4} \] - To subtract these fractions, we need a common denominator. The least common multiple of 9 and 4 is 36: \[ \Delta E_{21} = \left(\frac{4E_0}{9} \cdot \frac{4}{4}\right) - \left(\frac{E_0}{4} \cdot \frac{9}{9}\right) = \frac{16E_0}{36} - \frac{9E_0}{36} = \frac{7E_0}{36} \] 5. **Relate Energy Change to Wavelength for Transition \(L_2 \to L_1\)**: - Using Planck's law again: \[ \Delta E_{21} = \frac{hc}{\lambda_1} \] - Setting the energy change equal to the energy of the emitted photon gives: \[ \frac{7E_0}{36} = \frac{hc}{\lambda_1} \] - Rearranging gives us: \[ \lambda_1 = \frac{hc}{\frac{7E_0}{36}} = \frac{36hc}{7E_0} \] 6. **Relate the Two Wavelengths**: - From the previous steps, we have: \[ \lambda = \frac{4hc}{3E_0} \] - Now, we can express \(\lambda_1\) in terms of \(\lambda\): \[ \lambda_1 = \frac{36hc}{7E_0} = \frac{36}{7} \cdot \frac{hc}{E_0} = \frac{36}{7} \cdot \frac{4}{3} \lambda = \frac{48}{7} \lambda \] ### Final Answer: The wavelength of emission for the transition \(L_2 \to L_1\) is: \[ \lambda_1 = \frac{48}{7} \lambda \]
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