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For the reaction, 2N2O5rarr4NO2+O2 S...

For the reaction,
`2N_2O_5rarr4NO_2+O_2`
Select the correct statement

A

Rate of formation of `O_2` is same as rate of formation of `NO_2`

B

Rate of disappearance of `N_2O_5` is two times the rate of formation of `NO_2`

C

Rate of formation of `O_2` is 0.5 time rate disappearance of `N_2O_5`

D

Rate of formation of `NO_2` is equal to rate of disappearance of `N_2O_5`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction \(2N_2O_5 \rightarrow 4NO_2 + O_2\), we need to analyze the rates of formation and disappearance of the reactants and products involved in the reaction. ### Step-by-Step Solution: 1. **Write the Balanced Reaction**: The balanced chemical equation is: \[ 2N_2O_5 \rightarrow 4NO_2 + O_2 \] 2. **Identify the Rates of Change**: The rate of reaction can be expressed in terms of the change in concentration of the reactants and products over time. For the reaction, we can denote: - Rate of disappearance of \(N_2O_5\) as \(-\frac{1}{2} \frac{d[N_2O_5]}{dt}\) - Rate of formation of \(NO_2\) as \(\frac{1}{4} \frac{d[NO_2]}{dt}\) - Rate of formation of \(O_2\) as \(\frac{1}{1} \frac{d[O_2]}{dt}\) 3. **Relate the Rates**: From the stoichiometry of the reaction: - The rate of disappearance of \(N_2O_5\) is twice the rate of formation of \(NO_2\) and half the rate of formation of \(O_2\). - Therefore, we can write: \[ -\frac{1}{2} \frac{d[N_2O_5]}{dt} = \frac{1}{4} \frac{d[NO_2]}{dt} = \frac{1}{2} \frac{d[O_2]}{dt} \] 4. **Express the Relationships**: From the above relationships, we can derive: - The rate of formation of \(O_2\) is \(0.5\) times the rate of disappearance of \(N_2O_5\): \[ \frac{d[O_2]}{dt} = 0.5 \left(-\frac{d[N_2O_5]}{dt}\right) \] 5. **Conclusion**: Based on the stoichiometric coefficients and the rates of change, we can conclude that the rate of formation of \(O_2\) is indeed \(0.5\) times the rate of disappearance of \(N_2O_5\). Therefore, any statement claiming otherwise would be incorrect. ### Final Answer: The correct statement is that the rate of formation of \(O_2\) is \(0.5\) times the rate of disappearance of \(N_2O_5\). ---
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AAKASH INSTITUTE-CHEMICAL KINETICS-EXERCISE
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  2. Unit of rate of a reaction is

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  4. What is the unit of rate constant of n^(th) order of the reaction ?

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  8. The rate of reaction is always equal to the rate constant. The order o...

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  12. In a zero order reaction , 20% of the reaction complete in 10 s. How m...

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  13. If the half - life of the first order reaction is 50 s, what be the va...

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  14. In a first order reaction , on plotting a graph between t(1//2) and co...

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