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The ionization energy of H-atom is 13.6...

The ionization energy of H-atom is `13.6eV`. Calculate the is ionization energy of `Li^(+2)`ion-

Text Solution

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`Li overset(-e^(-))Li^(+) overset(e^(-)) Li^(2+) overset(e^(-))to Li^(3+)`
Total energy required `=1.96 xx 106(4)=19600"kJ mol"^(-1)`
`I.E_(1)=520kJ mol^(-1), I.E_(3)=(1312 xx Z^(2))/(n^(2))=(1312 xx 9)/(1) =11808`
`I.E_(1)+I.E_(3)=12328kJ mol^(-1)`
`I.E_(2)=19600-12328=7272"kJ mol"^(-1)`
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