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Calculate the work done when 1 mole of a...

Calculate the work done when `1` mole of a perfect gas is compressed adiabatically . The initial pressure and volume of the gas are `10^(5)N//m^(2)` and ` 6` litre respectively. The final volume of the gas is `2` litres. Molar specific heat of the gas at constant volume is `(3R)/(2) [(3)^(5//3) = 6.19]`

Text Solution

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For an adiabatic change `PV^(gamma)` = constant `P_(1)V_(1)^(gamma) = P_(2)V_(2)^(gamma)`.
As molar specific heat of gas at constant volume `C_(v) = (3)/(2)R`
`C_(P) = C_(V) + R = (3)/(2)R + R = (5)/(2)R implies gamma = (C_(P))/(C_(V)) = (5/2R)/(3/2R) = (5)/(3)`
`therefore P_(2) = [(V_(1))/(V_(2))]^(gamma) P_(1) = [(6)/(2)]^(5//3) xx 10^(5) = (3)^(5//3) xx 10^(5) = 6.19 xx 10^(5) N//m^(2)`
Work done ` W= (1)/(1-gamma) [P_(2)V_(2)- P_(1)V_(1)] = (1)/(1-(5//3)) [6.19 xx 10^(5) xx 2 xx 10^(-3) - 10^(-5) xx 6 xx 10^(-3)]`
`= -[(2xx10^(2)xx3)/(2) (6.19-3)] = -3xx10^(2) xx 3.19 = -957` joules
-ive sign shows external of work done on the gas
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