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Which of the following reactions of an a...

Which of the following reactions of an alcohol does not involve O-H bond breaking:

A

Reaction with alkali metals

B

reaction with an acyl chloride

C

reaction with sulphonyl chloride

D

reaction with conc. Sulphuric acid

Text Solution

Verified by Experts

The correct Answer is:
D

`-underset(|)overset(H)overset(|)(C)-underset(|)overset(OH)overset(|)(C)-underset(-HOH)overset(Conc.H_(2)SO_(4))to-underset(|)(C)=underset(|)(C)-`
This reaction involve breaking of `'C-O'` bond not `'O-H'` bond.
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BANSAL-ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION -Exercise 1
  1. The solubility of lower alcohols in water is due to

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  2. Conversion of CH(3)OH to CH(3)COOH can suitablly be carried out with t...

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  3. Which of the following reactions of an alcohol does not involve O-H bo...

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  4. Alkyl chloride is formed when alcohol is treated with HCl in presence ...

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  5. When ethyl alcohol reacts with acetic acid, the products formed are

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  6. Methyl alcohol reacts with phosphorus to form-

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  7. The-OH group of Methyl alcohol cannot be replaced by chlorine by the t...

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  8. Reaction of alcohol does not show cleavage of R-O linkage-

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  9. Replacement of -OH group in alcohol by -Cl cannot be carried out with...

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  10. Which alcohol does not give a ketone on oxidation-

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  11. A compound X with molecular formula C(3)H(8)O can be oxidised to a com...

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  12. Tertiary alcohols are resistance to oxidation because:

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  13. The number of alkanols and ethers represented by the molecular formula...

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  14. Which is mixmatched-

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  15. Diethyl ether is metamer of -

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  16. Anhydrides of alcohol are nothing but -

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  17. Electron pair donating tendency is maximum in-

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  18. Which of the following is a cyclic ether-

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  19. In which case the product is neither a cyclic ether nor open chain sym...

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  20. In order to obtain diethyl ether from ethanol, the latter is taken in-

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