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For making (CH(3))(3)C-O-C(2)H(5) the id...

For making `(CH_(3))_(3)C-O-C_(2)H_(5)` the ideal combination is-

A

`(CH_(3))_(3)CON a and C_(2)H_(5)Br`

B

`(CH_(3))_(3)CBr and C_(2)H_(5)ON a`

C

both the above

D

None

Text Solution

Verified by Experts

The correct Answer is:
A

(Williumson's synthysis)
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-overset(ө)(O)overset(o+)(Na)+overset(delta-)(Br)-overset(delta+)(CH_(2))-CH_(3)toCH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OCH_(2)CH_(3)`
`underset(3^(@)-"alkyl halide")(CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-Br)+overset(o+)(N)aoverset(ө)(O)C_(2)H_(5)toCH_(3)-underset(CH_(2))underset(||)overset(CH_(3))overset(|)(C)+HOC_(2)H_(5)`
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BANSAL-ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION -Exercise 1
  1. In which case the product is neither a cyclic ether nor open chain sym...

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  2. In order to obtain diethyl ether from ethanol, the latter is taken in-

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  3. For making (CH(3))(3)C-O-C(2)H(5) the ideal combination is-

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  4. Mixed ether will not be formed in the reaction-

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  5. In which case ether is formed-

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  6. Diethyl ether acts as a

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  7. Ethers like alcohols do not form strong.. . Bonding. Hence they are mo...

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  8. The compound obtained by the reaction of diethyl ether with chlorine i...

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  9. Diethyl ether absorbs oxygen to form-

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  10. Ethers in contact with air for a long time form peroxides. The presenc...

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  11. Diethyl Ether reacts with chlorine in the dark to form-

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  12. Ether does not form oxonium salt on reaction with-

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  13. The ordinary alkyl ethers are cleaved by-

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  14. The decomposition of ethers by KI or HBr is called-

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  15. Ether is not formed in this reaction-

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  16. Unsymmetrical ethers are best prepared by-

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  17. Which of the followig is used as an additive by fire departments under...

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  18. In the Williamson's synthesis for diethyl ether, which species workds ...

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  19. The structure of the compounds formed by the the reaction of diethyl e...

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  20. Ether bottles should not be kept open in air because-

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