Home
Class 12
CHEMISTRY
Assertion (A): 2,6-Dimethyl-4-nitropheno...

Assertion (A): 2,6-Dimethyl-4-nitrophenol (I) is more acidic than 3,5-dimethyl-4-nitrophenol (II).
Reason (R ): It is due to the steric inhibition of the resonance of `(-NO_(2))` group with two (Me) groups in (II).

A

If both statement-I & statement-II are true & the statement-II is a correct explanation of the statement-I

B

if both statement-I & statement-II are true but statement-II is not a correct explanation of the statement-I

C

If statement-I is true but the statement-II is false.

D

If statement-I is false but the statement-II is true.

Text Solution

Verified by Experts

The correct Answer is:
A
Promotional Banner

Topper's Solved these Questions

  • ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION

    BANSAL|Exercise Exercise 3|28 Videos
  • ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION

    BANSAL|Exercise Exercise 1|86 Videos
  • CARBOXYLIC ACID DERIVATIVES

    BANSAL|Exercise Exercise 3|23 Videos

Similar Questions

Explore conceptually related problems

" 4-nitrophenol is more acidic than "4" -methylphenol.Give reason "

(A) 4-Nitrophenol is more acidic than 2,4,6-trinitrophenol (R ) Phenol is weaker acid than carbonic acid.

Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.

Assertion (A) : Ph overset (o+)(N_2) Br^(Θ) couples with N, N -dimethyl aniline (I) but not with 2,6, -dimethyl- N,N -dimethuyl aniline (II) Reason (R ): Due to steric inhibition of resonce , the p-potion of (II) is not sufficiently activated fro the coupling reation. Due to steric inhibition of resonamne, the p-position of (II) is not sufficiently activated for the coupling reaction.

Assertion: Salicyclic acid is much strogest than its m-p -isomers and benzoic acid itself. Reason: It is due to steric inhibitation to resonance, as -OH group forces -COOH out of the plane of ring.

Write the IUPAC name of \(CH_{2}=CH-C(CH_{3})_{2}-OH\) . b) 4 -nitrophenol is more acidic than 4 -methylphenol. Give reason.

Assertion : 2,4-Dimethyl hex-2-ene has 4 stereoisomer Reason : It show geometrical isomerism

BANSAL-ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION -Exercise 2
  1. Statement-I: Statement-II: p-NO(2)-C(6)H(4)O^(-) is a stronger n...

    Text Solution

    |

  2. Statement-I: Statement-II Phenol cannot be chlorinated because ...

    Text Solution

    |

  3. Assertion (A): 2,6-Dimethyl-4-nitrophenol (I) is more acidic than 3,5-...

    Text Solution

    |

  4. Statement-I: Diphynyl ether (I) on dinitration gives the

    Text Solution

    |

  5. Statement-I: Reduction potential value (E^(@)) of o-benzoquine (I) is...

    Text Solution

    |

  6. Statement-I: Ethers o reaction with air and light form hydroperoxides....

    Text Solution

    |

  7. HBO. Oxymericuration-demercuration and acid catalysed hydration will n...

    Text Solution

    |

  8. In the reaction sepuence, CaC(2) overset(H(2)O)rarrAunderset(Hg^(2+))o...

    Text Solution

    |

  9. Compound which gives alcohol on reduction is/are

    Text Solution

    |

  10. Select the correct synthesis products

    Text Solution

    |

  11. Lucas test is used to make distinguation between 1^(@), 2^(@) and 3^(@...

    Text Solution

    |

  12. End-product of which of following reaction give positive Iodoform test...

    Text Solution

    |

  13. Dehydration of alcohols take place more rapidly with POCl(3) than with...

    Text Solution

    |

  14. Consider the following compound A (below) Select the correct statement...

    Text Solution

    |

  15. Which of the following are possible products in the above reaction?

    Text Solution

    |

  16. Products form by following reactions are

    Text Solution

    |

  17. C(2)H(5)NH(2)underset("reagent")overset("Tilden")to(i)overset(NH(3))to...

    Text Solution

    |

  18. Which of the following reaction represent major product.

    Text Solution

    |

  19. Which of the following will get oxidised by Br(2)//KOH into carboxylic...

    Text Solution

    |

  20. Diethyl ether reacts with PCl(5) to form

    Text Solution

    |