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End-product of which of following reacti...

End-product of which of following reaction give positive Iodoform test.

A

`H-overset(O)overset(||)(C)-Clunderst((ii).H^(o+))overset((i).CH_(3)MgBr("excess"))to`

B

`Ph-overset(O)overset(||)(C)-O-Etunderset((ii)H^(+))overset((i)CH_(3)MgBr("excess"))to`

C

`H-overset(O)overset(||)(C)-O-Etunderset((ii).H^(o+))overset((i). CH_(3)MgBr("excess"))to`

D

`CH_(3)-overset(O)overset(||)(C)-Hunderset((ii)H^(+))overset((i).CH_(3)MgBr("excess"))to`

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

`-`Iodoform test Haloform test is test of `-overset(O)overset(||)(C)-CH_(3),-underset(H)underset(|)overset(OH)overset(|)(C)-CH_(3)` group.
`-overset(Theta)(C)H_(3)` of `CH_(3)MgBr` work work as nuclephile


(C). `H-overset(O)overset(||)(C)-OE tunderset((2)H^(o+))overset((1).CH_(3)MgBr("exess"))tounderset("Give Iodoform test")(H-underset(CH_(3))underset(|)overset(OH)overset(|)(C)-CH_(3)+underset("Give Iodoform test")(HO-Et`
(D). `CH_(3)-overset(O)overset(||)(C)-H`
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BANSAL-ALCOHOL, ETHERS & PHENOL, OXIDATION & REDUCTION -Exercise 2
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  6. Which of the following are possible products in the above reaction?

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  7. Products form by following reactions are

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  8. C(2)H(5)NH(2)underset("reagent")overset("Tilden")to(i)overset(NH(3))to...

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  9. Which of the following reaction represent major product.

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  10. Which of the following will get oxidised by Br(2)//KOH into carboxylic...

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  11. Diethyl ether reacts with PCl(5) to form

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  12. Which method is useful for the synthesis of ether?

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  13. Which is/are correct statement?

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  14. In the reaction the intermediate (s) is/are

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  15. CH(3)-underset(CH(3))underset(|)(C)H-CH=CH(2)=overset("Reagent")toAlco...

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