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Amongst [TiE(6)]^(2-), [CoF(6)]^(3-), Cu...

Amongst `[TiE_(6)]^(2-), [CoF_(6)]^(3-), Cu_(2)Cl_(2)` and `[NiCl_(4)]^(2-)` [Atomic no. `Ti = 22, Co = 27, Cu = 29, Ni = 28`] the colourless species are :
(A) `[TiF_(6)]^(2-)` and `[Cu_(2)Cl_(2)]`
(B) `Cu_(2)Cl_(2)` and `[NiCl_(4)]^(2-)`
(C) `[TiF_(6)]^(2-)` and `[CoF_(6)]^(3-)`
(D) `[CoF_(6)]^(3-)` and `[NiCl_(4)]^(2-)`

A

`TiF_(6)^(2-) & Cu_(2)Cl_(2)`

B

`Cu_(2)Cl_(2) & NiCl_(4)^(2-)`

C

`TiF_(6)^(2-) & CoF_(6)^(3-)`

D

`CoF_(6)^(3-) & NiCl_(4)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Due to the absence of unpaired electron `TiF_(6)""^(-2) & Cu_(2)Cl_(2)` colouless species.
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BANSAL-D AND F BLOCK ELEMENTS-Exercise-1 (Single Correct Choice Type)
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  2. The lanthanide contraction is responsible for the fact that

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  7. Identify the incorrect statement among the following.

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  8. Which of the following ion has the maximum magnetic moment?

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  11. What is the general electronic configuration of transition elements

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  12. Knowing that the chemistry of lanthanoids (Ln) is dominated by its +3 ...

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  14. In context of the lanthanoids, which of the following statements is no...

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