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In context with the transition elements,...

In context with the transition elements, which of the following statements is incorrect ?

A

In the highest oxidation states, the transition metal show basic character and form cationic complexes

B

In the highest oxidation states of the first five transitio elements (Sc to Mn), all the 4s and 3d electrons are used for bonding

C

Once the d^(5) configuration is exceeded, the tendency to involve all the the 3d electrons in bonding decreases.

D

In addition to the normal oxidation states, the zero oxidation state is also show by these element in complexes

Text Solution

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The correct Answer is:
A

In the highest oxidation states, the transition metal shows acidic character.
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BANSAL-D AND F BLOCK ELEMENTS-Exercise-1 (Single Correct Choice Type)
  1. Which of the following ion has the maximum magnetic moment?

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  2. Transition elements are usually characterised by variable oxidation st...

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  3. In context with the transition elements, which of the following statem...

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  4. What is the general electronic configuration of transition elements

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  5. Knowing that the chemistry of lanthanoids (Ln) is dominated by its +3 ...

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  6. The highest oxidation state achieved by trantion metal is given by -

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  7. In context of the lanthanoids, which of the following statements is no...

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  8. The equilibrium Cr(2)O(7)^(2-)hArr 2CrO(4)^(2-)

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  9. When the same amount of Zn is treated with excess of H(2)SO(4) and exc...

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  10. (NH(4))(2)Cr(2)O(7)( Ammonium dichromate ) is used in fire works. The ...

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  11. The d-block elements which is a liquid at room temperature, having hig...

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  12. Coinage metals show the properties of

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  13. Cr(2)O(7)^(2-)underset(Y)overset(X)hArr 2CrO(4)^(2-)X and Y are respec...

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  14. CrO(3) dissolves in aqueous NaOH to give:

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  15. An ornament of gold having 75% of gold, is of carat.

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  16. Solution of MnO(4)^(-) is purple-coloured due to :

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  17. Transition elements having more tendency to form complex than represen...

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  18. uarr Y(g)overset(KI)(larr)CuSO(4)overset(dilH(2)SO(4))(rarr)X(Bluecolo...

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  19. The actinoids exhibit more number of oxidation states in general than ...

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  20. x,y and z are respectively

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