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For the reaction at 298 K A(g) + B(g)...

For the reaction at 298 K
`A(g) + B(g) iff C(g)+ D(g)`
`DeltaH^(@) = -29.8 Kcal, DeltaS^(@) = - 0.1 Kcal //K`
Calculate `DeltaG^(@)` and K.

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To solve the problem, we need to calculate the standard Gibbs free energy change (ΔG°) and the equilibrium constant (K) for the given reaction at 298 K. ### Step-by-Step Solution: 1. **Identify the given values**: - ΔH° = -29.8 Kcal - ΔS° = -0.1 Kcal/K - Temperature (T) = 298 K 2. **Convert ΔH° and ΔS° to consistent units**: Since ΔH° and ΔS° are given in Kcal, we can use them directly. However, it is often useful to convert them to Joules for standard calculations: - ΔH° = -29.8 Kcal × 4184 J/Kcal = -124,000 J - ΔS° = -0.1 Kcal/K × 4184 J/Kcal = -418.4 J/K 3. **Use the Gibbs free energy equation**: The relationship between ΔG°, ΔH°, and ΔS° is given by the equation: \[ ΔG° = ΔH° - TΔS° \] 4. **Substitute the values into the equation**: \[ ΔG° = -124,000 J - (298 K)(-418.4 J/K) \] 5. **Calculate TΔS°**: \[ TΔS° = 298 K × -418.4 J/K = -124,000 J \] 6. **Calculate ΔG°**: \[ ΔG° = -124,000 J + 124,000 J = 0 J \] 7. **Calculate the equilibrium constant (K)**: The relationship between ΔG° and K is given by: \[ ΔG° = -RT \ln K \] Where R = 8.314 J/(mol·K). Since ΔG° = 0, we can rearrange the equation: \[ 0 = -RT \ln K \] This implies: \[ \ln K = 0 \] 8. **Solve for K**: Since \(\ln K = 0\), we can exponentiate both sides: \[ K = e^0 = 1 \] ### Final Results: - ΔG° = 0 J - K = 1

To solve the problem, we need to calculate the standard Gibbs free energy change (ΔG°) and the equilibrium constant (K) for the given reaction at 298 K. ### Step-by-Step Solution: 1. **Identify the given values**: - ΔH° = -29.8 Kcal - ΔS° = -0.1 Kcal/K - Temperature (T) = 298 K ...
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