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A solution containing 3.1 g of BaCI(2) ...

A solution containing 3.1 g of `BaCI_(2)` in this solution. (`K_(b)` for water= 0.52 K `m^(-1)`. Molar mass `BaCI_(2)=208.3 mol^(-1)`).

Text Solution

Verified by Experts

The correct Answer is:
45.1

`"Molality of solution (m)"=W_(B)/(M_(B)xxW_(A))`
`W_(B)=3.1g, W_(A)=250 g =0.25 kg, M_(B)=208.3 " g mol"^(-1)`
`m=((3.1g))/((208.3" g mol"^(-1))xx(0.25 kg))=0.05952" kg mol"^(-1)=0.05952 m.`
`"For the solution", Delata T_(b)=iK_(b)m`
`or" " i=(DeltaT_(b))/(K_(b)xxm),DeltaT_(b)=100.083^(@)C-100^(@)C=0.083 K`
`K_(b)=0.52Km^(-1),m=0.05952 m`
`therefore" "i=((0.083 K))/((0.52"Km"^(-1))xx(0.05952m))=2.68`
`"Ratio of i and m (i/m)"=(2.68)/(0.05952)=45:1`
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