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It is tempting to think that all possibl...

It is tempting to think that all possible transition are permissible and that an atomic spectrum arises from the transition of an electron from any initial orbital to any other orbital .However this is not so because a photon a photon has as intrinsic spin angular momentum of `sqrt(2) h// 2pi` corresponding to `S = 1` although it has no charge and no rest mass
On the other hand , an electron has got two type of angular momentum: orbital angular momentum
`L = [sqrt(l(l+1))] h//2pi`,and spin angular momentum `L_(1) = sqrt(s(s + 1)) h//2pi` arising from orbital motion and spin motion of the electron during any electronic transition must compensate for the angular momentum carried away by the photon .To satisfy this condition the different between the azimuthal quantum number of the orbital within which the transition take place must differ by 1.thus, an electron in a d-orbital `(l = 2)` cannot make a transition into as s-orbital `(l = 0)`because the photon cannot carry away enough angular momentum
The maximum orbital angular momentum of an electron with `n = 5` is

A

`sqrt(2) (h)/(2pi)`

B

`sqrt(6)(h)/(2pi)`

C

`sqrt(12)(h)/(2pi)`

D

`sqrt(20)((h)/(2pi))`

Text Solution

Verified by Experts

The correct Answer is:
C

`L = sqrt(l(l+1)) (h)/(2pi)`
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