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The radial distribution functions [P(r)]...

The radial distribution functions `[P(r)]` is used to determine the most probable radius, which is used to find the electron in a given orbital `(dP(r))/(dr)` for `1s`-orbital of hydrogen like atom having atomic number `Z`, is `(dP)/(dr)=(4Z^(3))/(a_(0)^(3))(2r-(2Zr^(2))/(a_(0)))e^(-2Zr//a_(0))` :

A

At the point of maximum value of radial distribution function `(dP(r))/(dr)=0`, one antinode is present

B

Most probable radius of `Li^(2+)` is `(a_(0))/(3)pm`

C

Most probable radius of `He^(+)` is `(a_(0))/(2)pm`

D

Most probable radius of hydrogen atom is `a_(0)pm`

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The correct Answer is:
A, B, C, D
at point of max value of radial distribution function `(dp)/(dr) = 0`
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The Schrodinger wave equation for H-atom is nabla^(2) Psi = (8pi^(2)m)/(h^(2)) (E-V) Psi = 0 Where nabla^(2) = (del^(2))/(delx^(2)) +(del^(2))/(dely^(2)) +(del^(2))/(delz^(2)) E = Total energy and V=potential energy wave function Psi_(((r, theta,phi)))R_((r))Theta_((theta))Phi_((phi)) R is radial wave function which is function of ''r'' only, where r is the distance from nucleus. Theta and Phi are angular wave function. R^(2) is known as radial probability density and 4pir^(2)R^(2)dr is known as radial probability function i.e., the probability of finding the electron is spherical shell of thickness dr. Number of radial node =n -l - 1 Number of angular node = l For hydrogen atom, wave function for 1s and 2s-orbitals are: Psi_(1s) = sqrt((1)/(pia_(0)^(a)))e^(-z_(r)//a_(0)) Psi_(2s) = ((Z)/(2a_(0)))^(½) (1-(Zr)/(a_(0)))e^(-(Zr)/(a_(0))) The plot of radial probability function 4pir^(2)R^(2) aganist r will be: Answer the following questions: The value of radius 'r' for 2s atomic orbital of H-atom at which the radial node will exist may be given as:

The Schrodinger wave equation for H-atom is nabla^(2) Psi = (8pi^(2)m)/(h^(2)) (E-V) Psi = 0 Where nabla^(2) = (del^(2))/(delx^(2)) +(del^(2))/(dely^(2)) +(del^(2))/(delz^(2)) E = Total energy and V=potential energy wave function Psi_(((r, theta,phi)))R_((r))Theta_((theta))Phi_((phi)) R is radial wave function which is function of ''r'' only, where r is the distance from nucleus. Theta and Phi are angular wave function. R^(2) is known as radial probability density and 4pir^(2)R^(2)dr is known as radial probability function i.e., the probability of finding the electron is spherical shell of thickness dr. Number of radial node =n -l - 1 Number of angular node = l For hydrogen atom, wave function for 1s and 2s-orbitals are: Psi_(1s) = sqrt((1)/(pia_(0)^(a)))e^(-z_(r)//a_(0)) Psi_(2s) = ((Z)/(2a_(0)))^(½) (1-(Zr)/(a_(0)))e^(-(Zr)/(a_(0))) The plot of radial probability function 4pir^(2)R^(2) aganist r will be: Answer the following questions: What will be number of angular nodes and spherical nodes for 4f atomic orbitals respectively.

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