Home
Class 11
CHEMISTRY
Two isomeric compound 'A' and 'B' have t...

Two isomeric compound 'A' and 'B' have the formula `C_(3)H_(6)Cl_(2)`. With aq KOH solution'A' gives propionaldehyde and 'B' gives acetone. Than 'A' and 'B' are

A

`CH_(3)-C Cl_(2)-CH_(3)` and `CH_(3)-CH_(2)-CHCl_(2)`

B

`CH_(3)-CHCl-CHCl_(2)` and `CH_(3)-CH_(2)-CHCl_(2)`

C

`CH_(3)-CH_(2)-CHCl_(2)` and `CH_(3)- C Cl_(2)-CH_(3)`

D

`CH_(3)-CHCl-CHCl_(2)` and `CH_(3)-C Cl_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
3

Terminal geminal dihalides gives aldehydes and that of other geminal dihalides gives ketones with aq. KOH A)
B) `C-overset(CI)overset(|)underset(CI)underset(|)C-C`
Promotional Banner

Topper's Solved these Questions

  • CARBONYL COMPOUNDS

    NARAYNA|Exercise LEVEL -III|54 Videos
  • CARBONYL COMPOUNDS

    NARAYNA|Exercise STATEMENT TYPE|24 Videos
  • CARBONYL COMPOUNDS

    NARAYNA|Exercise LEVEL -1 (C.W)|20 Videos
  • BENZENE

    NARAYNA|Exercise Level-6|121 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    NARAYNA|Exercise EXERCISE -4|54 Videos

Similar Questions

Explore conceptually related problems

Two isomeric compounds A and B have some molecualr formula C_(3)H_(5)N . It was found that

Two isomeric aromatic compounds A and B have the molecular formula C_(7)H_(7)OH . A gives purple colour with FeCl_(3) solution while B does not. What are A and B ?

Two isomeric compounds, (A) and (B), have the same formula, C_(11)H_(13)OCI . Both are unsaturated, yield the same compound (C) on catalytic hydrogenation, and produce 4-chloro-3-ethoxybenzoic acid on vigorous oxidation. (A) exists in geometrical isomers, (D) and (E), but not (B). Give structures of (A) to (E) with proper reasoning.

When H_(2) is added to two isomeric alkenes A and B having molecular formula C_(5)H_(9)Cl , A gives optically inactive compound while B gives a chiral compound. The two isomers are

Two isomeric compounds(A) and (B) have molecular formula C_(6)H_(10) . Oxidation of (A) gives mixture of butanoic and acetic acids, whereas compound (B) gives hexa-1,6-dioicacid. What are (A) and (B)?

Two isomeric compounds A and B have molecular formula C_(3)H_(6)O . A responds to silver mirror test but not B. B on treatment with Zn ( Hg) and conc. HCl gives propane. A and B are respectively.

Two compounds [A] and [B] have molecular formula C_(2)H_(6)O. On reacting with HI [A] gives alkyl iodide and water while [B] gives alkyl iodide and alcohol . What are the compounds [A] and [B] ? Write the reactions involved.

NARAYNA-CARBONYL COMPOUNDS-LEVEL-II(C.W)
  1. Two isomeric compound 'A' and 'B' have the formula C(3)H(6)Cl(2). With...

    Text Solution

    |

  2. A new C-C bond formation is possible in :

    Text Solution

    |

  3. The enol form of acetone after treatment with D(2)O gives:

    Text Solution

    |

  4. (a) Write the reagent used in the following : C(6)H(5)COCH(3)overset...

    Text Solution

    |

  5. Aoverset(Cl(2))rightarrow C Cl(3)CHOoverset(NaOH)rightarrow B.In this ...

    Text Solution

    |

  6. C(6) H(5)CH(3)overset((1)CrO(2)Cl(2)//CS(2))underset(H(3)O^(+))rightar...

    Text Solution

    |

  7. A substance C(4)H(10)O yields on oxidation a compound C(4)H(8)O which ...

    Text Solution

    |

  8. Which of the following has the most acidic hydrogen?

    Text Solution

    |

  9. What are products of the following crossed cannizaro reactions

    Text Solution

    |

  10. Identify the product of the following condensation reaction

    Text Solution

    |

  11. By cannizaro reaction A change to B and C as gives Identify 'A'

    Text Solution

    |

  12. Benzaldehyde and acetone in 2: 1 molar ratio is treated with base Ba(O...

    Text Solution

    |

  13. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

    Text Solution

    |

  14. C(3)H(8)Ooverset(O)underset(K(2)Cr(2)"O"//H)rarrC(3)H(6)Ooverset(I(2))...

    Text Solution

    |

  15. product is

    Text Solution

    |

  16. A compound (A) has a molecular formula C(2)Cl(3)OH. It reduces Fehling...

    Text Solution

    |

  17. The major product obtainned in the reaction

    Text Solution

    |

  18. On vigorous oxidaiton by permanganate solution (CH(3))(2)C=CHCH(2)CHO ...

    Text Solution

    |

  19. 4- heptanoneoverset(KMnO(4)//H^(+)//Delta)rightarrow A+B. Identify A ...

    Text Solution

    |

  20. Which of the following alkenes on ozonolysis give a mixture of ketones...

    Text Solution

    |