Home
Class 12
CHEMISTRY
A graph between log t((1)/(2)) and log a...

A graph between `log t_((1)/(2))` and log a (abscissa), a being the initial concentration of A in the reaction For reaction `Ato`Product, the rate law is :

A

`(-d[A])/(dt)=K`

B

`(-d[A])/(dt)=K[A]`

C

`(-d[A])/(dt)=K[A]^2`

D

`(-d[A])/(dt)=K[A]^3`

Text Solution

Verified by Experts

The correct Answer is:
C

`t_(1//2)=Ka^(1-n)`,n being order K=Rate constant
log `t_(1//2)=log K+(1-n) log a`
1-n=-1
n=2
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

Following is the graph between log t_(1//2) and log a ( a initial concentration) for a given reaction at 27^(@)C . Find the order of reaction.

Following is the graph between log T_(50) and log a ( a = initial concentration) for a given reaction at 27^(@)C . Hence order is

Following is the graph between log T_(50) and log a (a = initial concentration) for a given reaction at 27^(@)C . Hence, order is

The graph between log t_(1//2) and log a at a given temperature is Rate of this reaction will …….with passage of time

For a reaction A rarr Products, a plot of log t_(1/2) ,versus log a is shown in figure. If the initial concentration of A is represented by a ,the order of the reaction is:-

Plotting log_(10)t_(1//2) against log _(10)[A_0] (where A_0 is the initial concentration of a reactant) for a fist order reaction the slope will be

For zero order reaction , t_(1//2) will be ( A_0 is the initial concentration , K is rate constant)

RESONANCE-RANK BOOSTER-All Questions
  1. 1 g of arsenic dissolved in 86 g of benzene brings down the freezing p...

    Text Solution

    |

  2. At a certain temperature, the first order rate constant k(1) is found ...

    Text Solution

    |

  3. A graph between log t((1)/(2)) and log a (abscissa), a being the init...

    Text Solution

    |

  4. A gaseous reaction A(2)(g) rarr B(g) + (1)/(2) C(g) shows increase in ...

    Text Solution

    |

  5. For a certain reaction the variation of rate constant with temperature...

    Text Solution

    |

  6. A reaction takes place in theee steps: the rate constant are k(1), k(2...

    Text Solution

    |

  7. In a certain reaction, 10% of the reactant decomposes in one hour, 20%...

    Text Solution

    |

  8. Some graph are sketched for the reactant decomposes in one hour, 20% i...

    Text Solution

    |

  9. Compounds A and B react with a common reagent with first order kinetic...

    Text Solution

    |

  10. The acitivity per ml of a solution of radioactive substances is x. How...

    Text Solution

    |

  11. A reaction with respect to X is zero order till the concentration is r...

    Text Solution

    |

  12. Consider the following statements and arrange in order of true/false a...

    Text Solution

    |

  13. For the reaction 2A+BtoC with the rate low (d[C])/(dt)=k[A]^(1)[B]^(-1...

    Text Solution

    |

  14. The half-period T for the decomposition of ammonia on tungsten wire, w...

    Text Solution

    |

  15. The substance undergoes first order decomposition.The decomposition fo...

    Text Solution

    |

  16. A certain reaction obeys the rate equation (in the integrated form) [C...

    Text Solution

    |

  17. A certain reaction A rarr B follows the given concentration (Molarity)...

    Text Solution

    |

  18. Consider the following case of competing 1^(st) order reactions. ...

    Text Solution

    |

  19. Assertion (A) : If the activation energy of a reaction is zero, temper...

    Text Solution

    |

  20. The rate law expresses the relationship of the rate of a reaction to t...

    Text Solution

    |