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Based on data given below, match column-...

Based on data given below, match column-I and column II
`3X(g)overset("250K,1atm")toX_3(g), DeltaH=-200 KJ//mol , DeltaS=-300 J//K//mol`
`X(l)overset("1atm,250K")toX(g), DeltaH_(vap)=10 KJ//mol`
`X_3(l)overset("500K,1atm")toX_3(g), DeltaH_(vap)=80 KJ//mol`
`X_3`(g,250 K , 1 atm )`toX_3`(g, 500 K, 1 atm) `DeltaH`=100KJ/mol,`DeltaS`=100 J/K/mol , `DeltaG`=60 KJ/mol Normal boiling point of X=250 K normal boiling point of `X_3`=500 K.
Enthalpy change and entropy change of cooling `X_3(l)` to lower temperature is neglible.

Text Solution

Verified by Experts

The correct Answer is:
A-r ; B-q ; C-s ; D-p


overall
`DeltaH=3xx10-200+100-80+0=300-200+100-80=-150` kJ/mol
`DeltaS=20-300+100-160+0=-240` J/mol/K
`DeltaG=0+(-125)+60+0+0=-65` kJ/mol
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