Home
Class 12
CHEMISTRY
In the fluorite structure if the radius ...

In the fluorite structure if the radius ratio is `(sqrt(3)/(2)-1)` how many ions does each cation touch?

A

4 anions

B

12 cations

C

8 anions

D

No cations

Text Solution

Verified by Experts

The correct Answer is:
B,C

In flourite structure, cations form the lattice & anions occupy each of tetrahedral voids.
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

In the fluorite structure the coordination number of Ca^(2+) ion is

In the Lewis structure for the selenite ion, SeO_(3)^(2-) , how many lone pairs are around the central atom?

Br^- ions form a close packed structure. If the radius of Br^– ions is 195 pm, calculate the radius of the cation that just fits into the tetrahedral hole. Can a cation A^+ having a radius of 82 pm be shipped into be octahedral hole of the crystal A^+ Br^– ?

'AB' has rock salt structure. Radius of cation is 100pm. If the radius of anion is 1.6 times that of cation then the edge length of unit cell "AB" will be

AB' has rock salt structure. Radius of cation is 100pm. If the radius of anion is 1.6 times that of cation then the edge length of unit cell "AB" will be

Early crystallographers had trouble solving the structures of inorganic solids using X-ray diffraction because some of the mathematical tools for analyzing the data had not yet been developed. Once a trial structure was proposed, it was relatively easy to calculate the diffraction pattern, but it was difficult to go the other way (from the diffraction pattern to the structure) if nothing was known a priori about the arrangement of atoms in the unit cell. It was important to develop some guidelines for guessing the coordination numbers and bonding geometries of atoms in crystals. The first such rules were proposed by Linus Pauling, who considered how one might pack together oppositely charged spheres of different radii. Pauling proposed from geometric considerations that the quality of the "fit" depended on the radius ratio of the anion and the cation. If the anion is considered as the packing atom in the crystal, then the smaller cation fills interstitial sites ("holes"). Cations will find arrangements in which they can contact the largest number of anions. If the cation can touch all of its nearest neighbour anions then the fit is good. If the cation is too small for a given site, that coordination number will be unstable and it will prefer a lower coordination structure. The table below gives the ranges of cation/anion radius ratios that give the best fit for a given coordination geometry. The radius of Ag^+ ion is 126pm and of I^- ion is 216pm. The coordination number of Ag^+ ion is:

RESONANCE-RANK BOOSTER-All Questions
  1. Following three planes (P(1), P(2), P(3)) in an fcc unit cell are show...

    Text Solution

    |

  2. In a AB unit cell (Rock salt type) assuming A^(+) forming fcc :

    Text Solution

    |

  3. In the fluorite structure if the radius ratio is (sqrt(3)/(2)-1) how m...

    Text Solution

    |

  4. The co-ordination number of FCC structure for metals is 12, since:

    Text Solution

    |

  5. An hcp and a ccp structure for a given element would be expected to ha...

    Text Solution

    |

  6. Assertion : An important feature of fluorite structure is that cations...

    Text Solution

    |

  7. Assertion :In NaCIcrystal each Na^(+) ion is tourching 6 CI^(-) ion bu...

    Text Solution

    |

  8. When an atom or an ion is missing from its nomal lattice site a lattic...

    Text Solution

    |

  9. Column-I and Column-II contains four entries each.Entries of Column-I ...

    Text Solution

    |

  10. A(2)B molecules(" molar mass " = 259.8 g//"ml") crystallises in a hex...

    Text Solution

    |

  11. In F.C.C. arrangement of identical spheres, distance between two neare...

    Text Solution

    |

  12. N2 and H2 are taken in 1:3 molar ratio in a closed vessel to attained ...

    Text Solution

    |

  13. The unit of equilibrium constant KC of a reaction is "mol"^(-2) boat^2...

    Text Solution

    |

  14. NH4COONH2 (s) hArr 2NH3(g)+CO(2)(g) If equilibrium pressure is 6 atm...

    Text Solution

    |

  15. A 10 litre box contains O3 and O2 at equilibrium at 2000 K. Kp=4xx10^(...

    Text Solution

    |

  16. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

    Text Solution

    |

  17. For the chemical reaction 3X(g)+Y(g) hArr X(3)Y(g), the amount of ...

    Text Solution

    |

  18. What is the minimum mass of CaCO3(s), below which it decomposes comple...

    Text Solution

    |

  19. For an equilibrium H2O(s) hArr H2O(l)which of the following statements...

    Text Solution

    |

  20. If two gases AB(2) and B(2)C are mixed, following equilibria are readi...

    Text Solution

    |