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The van der Waal's constant 'b' for N2 a...

The van der Waal's constant 'b' for `N_2` and `H_2` has the values 0.04 lit `"mol"^(-1)` and 0.025 lit `"mol"^(-1)`.The density of solid `N_2` is 1 g `cm^(-3)`.Assuming the molecules in the solids to be close packed with the same percentage void, the density of solid `H_2` would be (in `cm^(-3)`)

A

0.114

B

0.682

C

1.466

D

0.071

Text Solution

Verified by Experts

The correct Answer is:
A

`b_(N_2)/b_(H_2)=V_(N_2)/V_(H_2)=((M//d)_(N_2))/((M//d)_(H_2))implies d_(H_2)=0.040/0.025xx2/28=0.114`
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