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Adsorption is the presence of excess con...

Adsorption is the presence of excess concentration of any particular component at the surface of liquid a solid phase as compared to bulk.This is due to presence of residual forces at the surface of body.In the adsorption of hydrogen gas over a sample of charcoal, `1.12cm^3` of `H_2(g)` measured over S.T.P was found to absorb per gram of charcoal.Consider only monolayer adsorption.Density of `H_2` is 0.07gm/cc. In another experiment same 1 gm charcoal adsorbs 100 ml of 0.5M `CH_3COOH` to form monolayer and thereby the molarity of `CH_3COOH` reduces to 0.49.
`((3xx47.43)/(4pi))^(1//3)=2.24`
`(2.24)^2=5`
Molecule of acetic acids adsorbed-

A

`6.023xx10^20`

B

`6.023xx10^21`

C

`6.023xx10^22`

D

`6.023xx10^23`

Text Solution

Verified by Experts

The correct Answer is:
A

moles of acetic acid adsorbed `=0.5xx100/1000-0.49xx100/1000=10^(-3)` moles
so molecules adsorbed `=10^(-3)xx6.023xx10^23=6.023xx10^20` molecules.
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Adsorption is the presence of excess concentration of any particular component at the surface of liquid a solid phase as compared to bulk.This is due to presence of residual forces at the surface of body.In the adsorption of hydrogen gas over a sample of charcoal, 1.12cm^3 of H_2(g) measured over S.T.P was found to absorb per gram of charcoal.Consider only monolayer adsorption.Density of H_2 is 0.07gm/cc. In another experiment same 1 gm charcoal adsorbs 100 ml of 0.5M CH_3COOH to form monolayer and thereby the molarity of CH_3COOH reduces to 0.49. ((3xx47.43)/(4pi))^(1//3)=2.24 (2.24)^2=5 Specific surface are of charcoal is (cm^2//gm) -

Adsorption is the presence of excess concentration of any particular component at the surface of liquid a solid phase as compared to bulk.This is due to presence of residual forces at the surface of body.In the adsorption of hydrogen gas over a sample of charcoal, 1.12cm^3 of H_2(g) measured over S.T.P was found to absorb per gram of charcoal.Consider only monolayer adsorption.Density of H_2 is 0.07gm/cc. In another experiment same 1 gm charcoal adsorbs 100 ml of 0.5M CH_3COOH to form monolayer and thereby the molarity of CH_3COOH reduces to 0.49. ((3xx47.43)/(4pi))^(1//3)=2.24 (2.24)^2=5 Surface area of charcoal adsorbed by each molecule of (acetic soda) is-

Adsorption is the presence of excess concentration of any particular component at the surface of liquid a solid phase as compared to bulk.This is due to presence of residual forces at the surface of body.In the adsorption of hydrogen gas over a sample of charcoal, 1.12cm^3 of H_2(g) measured over S.T.P was found to absorb per gram of charcoal.Consider only monolayer adsorption.Density of H_2 is 0.07gm/cc. In another experiment same 1 gm charcoal adsorbs 100 ml of 0.5M CH_3COOH to form monolayer and thereby the molarity of CH_3COOH reduces to 0.49. ((3xx47.43)/(4pi))^(1//3)=2.24 (2.24)^2=5 What is the radius of adsorb hydrogen molecule-

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