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Assertion: In general, for an element, I...

Assertion: In general, for an element, `IE_(1) lt IE_(2) lt IE_(3)....`
Reason: After the removal of each succesive electron remaining electrons are held more tightly by the nucleus so removal of next electorn becomes difficult.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

Verified by Experts

The correct Answer is:
A
(A)Statement-1 and Statement-2 are correct. Statement-2 is correct explanation of Statement -1
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The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Successive ionisation energy of an atom is greater than previous one, because

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Correct order of ionisation potential of coinage metals is :

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . IE_(1) and IE_(2) of Mg metal are 178 and 348 kcal/mol respectively . The energy required for the given reaction is : Mg(g)rarr Mg^(+2)(G)+2e^(-)

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact the after the removal of the first electron, the atom changes into monovalent positive ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. as a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron. therefore, the value of second ionisation energy. (IE_(2)) , is greater than that of the first ionisatio energy (IE_(1)) . similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Q. IE_(1) and IE_(2) of Mg metal are 178 and 348 kcal/mol respectively. the energy required for the given reaction is: Mg(s) to Mg^(+2)+2e^(-)

Statement-I : IE_(3) of Mn is more than IE_(3) of Fe. Statement-II : After the removal of 2 electron Fe acquire half filled electronic configuration.

Assertion: Boron has a smaller first ionisation enthalpy than beryllium. Reason: The penetration of a 2s electron to the nucleus is more than the 2p electron, hence 2p electorn is more shielded by the inner core of electrons than the 2s electrons.

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