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Which of the following statements is inc...

Which of the following statements is incorrect ?

A

Cassiterite is an oxide ore of tin

B

Tin metal is obtained by the carbon reduction of black tin (purified ore of tin)

C

In the extraction of lead from galena, the roasting and self-reduction are carried out in the same furnance at different temperature.

D

Reducing agent of haematite in blast furnace is coke in upper part and CO in lower part of furnace

Text Solution

Verified by Experts

The correct Answer is:
D

(A)Cassiterite contains iron and manganese tungstate, called as Wol-framite.They have magnetic properties.
(B)Purified ore that contains 70% `SnO_2` is called black tin.
`SnO_2+2CtoSn+2CO` (carbon reduction)
(C )Roasting is done at moderater temperature in presence of air in reverberatory furnace.Then air supply is stopped and temperature is increased to melt the mass when self-reduction takes place.
(D)At 500-800 K(lower temperature range in the upper part of blast furnace)
`3Fe_2O_3+COto2Fe_3O_4+CO_2`
`Fe_3O_4+COto3Fe+4CO_2`
`Fe_2O_3+CO to 2FeO+CO_2`
At 900-1500 K (higher temperature range in the lower part of blast furnace):
`C+CO_2to2CO, FeO+COtoFe+CO_2`
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