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Nitrogen forms the largest number of oxi...

Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range of `N_(2)O` (O.S of nitrogen +1) through `NO, N_(2)O_(3),NO_(2),N_(2)O_(4)` "to" `N_(2)O_(5)` (O.S of nitrogen +5). Following points are improtant regarding the study of oxides of nitrogen.
(a) All oxides of nitrogen expect `N_(2)O_(5)` are endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen.
(b) The small electronegativity difference between oxygen and nitrogen make N-O bond easily breakle to give oxygen and hence oxides of nitrogen are said to be better oxidising agents.
(c) Expect `N_(2)O_(5)`, all are gases at ordinary temperature. `N_(2)O_(3)` is stable only at lower temperature (253K).
(d) Expect `N_(2)O` and NO which are neutal oxides, all are acidic oxides which dissolve in water forming coresponding oxy acids.
(e) They are also good example for illustrating the concept of resonance.
The gas which is acidic in nature is :

A

NO

B

`N_2O`

C

`NO_2`

D

both (A) and (C )

Text Solution

Verified by Experts

The correct Answer is:
C

`H_2O +2NO_2 to HNO_3 + HNO_2`
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