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Nitrogen forms the largest number of oxi...

Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen.They range from `N_2O`(O.S of nitrogen+1) through `NO, N_2O_3,NO_2,N_2O_4` to `N_2O_5`(O.S of nitrogen +5).
Following points are important regarding the study of oxides of nitrogen.
(a)All oxides of nitrogen except `N_2O_6` and endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen.
(b)The small electronegativity difference between oxygen and nitrogen make N-O bond easily breakable to give oxygen and hence oxides of nitrogen are said to be better oxidising agents.
(c )Except `N_2O_5`, all are gases at ordinary temperature. `N_2O_3` is stable only at lower temperature (253 K).
(d) Except `N_2O` and NO which are neutral oxides, all are acidic oxides which dissolve in water forming corresponding oxy acids.
(e)They are also good example for illustrating the concept the resonance.
Identify the incorrect statement.

A

In `N_2O_4` the N-N bond length is longer than the usual N-N single bond distance

B

`NO_2` molecule is angular with N-O distance equal to intermediate distance between a single and a double bond.

C

`N_2O` is a linear molecule and has a small dipole moment

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
D
(A)N-N bond length (1.75 Å) is longer than usual N-N single bond length which is believed to be due to `delta^-` charge and lone pair of electrons on N atoms which causes repulsion.

(C )`:N-=underset(sp)N:tounderset(ddot)overset(ddot)O:` and the structure suggests that it will have some dipole moment.
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Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range of N_(2)O (O.S of nitrogen +1) through NO, N_(2)O_(3),NO_(2),N_(2)O_(4) "to" N_(2)O_(5) (O.S of nitrogen +5). Following points are improtant regarding the study of oxides of nitrogen. (a) All oxides of nitrogen expect N_(2)O_(5) are endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen. (b) The small electronegativity difference between oxygen and nitrogen make N-O bond easily breakle to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (c) Expect N_(2)O_(5) , all are gases at ordinary temperature. N_(2)O_(3) is stable only at lower temperature (253K). (d) Expect N_(2)O and NO which are neutal oxides, all are acidic oxides which dissolve in water forming coresponding oxy acids. (e) They are also good example for illustrating the concept of resonance. The gas which is acidic in nature is :

The solid oxide of nitrogen is N_2 O .

Knowledge Check

  • Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen.They range from N_2O (O.S of nitrogen+1) through NO, N_2O_3,NO_2,N_2O_4 to N_2O_5 (O.S of nitrogen +5). Following points are important regarding the study of oxides of nitrogen. (a)All oxides of nitrogen except N_2O_6 and endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen. (b)The small electronegativity difference between oxygen and nitrogen make N-O bond easily breakable to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (c )Except N_2O_5 , all are gases at ordinary temperature. N_2O_3 is stable only at lower temperature (253 K). (d) Except N_2O and NO which are neutral oxides, all are acidic oxides which dissolve in water forming corresponding oxy acids. (e)They are also good example for illustrating the concept the resonance. Which of the following statement is correct for the oxides of nitrogen ?

    A
    Dinitrogen trioxide dissolves in potassium hydroxide forming potassium nitrate
    B
    Aqueous solution of nitrogen dioxide behaves both as a reducing agent and as an oxidising agent
    C
    Nitrous oxide is fairly soluble in cold water and turns blue litmus red
    D
    Nitrogen dioxide is an odd electron molecule and in the liquid phase, exists in equilibrium with the dimer `N_2O_4`

  • Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range from N_(2)O (O.S of nitrogen +1) through NO, N_(2)O_(3), NO_(2), N_(2)O_(4), " to " N_(2)O_(5) (O.S of nitrogen +5). Following points are important regarding the study of oxides of nitrogen (a) All oxides of nitrogen except N_(2)O_(5) are endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen. (b) The small electronegativity difference between oxygen and nitrogen make N - O bond easily breakble to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (c) Except N_(2)O_(5) , all are gases at ordinary temperature N_(2)O_(3) is stable only at lower temperature (253 K). (d) Except N_(2)O and NO which are neutral oxides, all are acidic oxides which dissolve in water forming corresponding oxy acids. (e) They are also good example for illustrating the concept of resonance Which of the following statements is correct for the oxides of nitrogen ?

    A
    Dinitrogen trioxide dissolves in potassium hydroxide forming potassium nitrate
    B
    Aqueous solution of nitrogen dioxide behaves both as a reducing agent and as an oxidising agent
    C
    Nitrous oxide is fairly soluble in cold water and turns blue litmus red
    D
    Nitrogen dioxide is not acidic oxide

  • Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range of N_(2)O (O.S of nitrogen +1) through NO, N_(2)O_(3),NO_(2),N_(2)O_(4) to N_(2)O_(5) (O.S of nitrogen +5). Following points are improtant regarding the study of oxides of nitrogen. (a) All oxides of nitrogen expect N_(2)O_(5) are endothermic as a large amount of energy is required to dissociate the stable molecule of oxygen and nitrogen. (b) The small electronegativity difference between oxygen and nitrogen make N-O bond easily breakle to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (c) Expect N_(2)O_(5) , all are gases at ordinary temperature. N_(2)O_(3) is stable only at lower temperature (253K). (d) Expect N_(2)O and NO which are neutal oxides, all are acidic oxides which dissolve in water forming coresponding oxy acids. (e) They are also good example for illustrating the concept of resonance. Which of the following statements is corect for the oxides of nitrogen?

    A
    Dinitrogen trioxide dissolves in potassium hydroxide forming potassium nitrate.
    B
    Aqueuous slution of nitrogen dixide behaves both as a reducing agent and as a oxidising agent.
    C
    Nitrogen oxide is fairly soluble in cold water and turns blue litmus red.
    D
    Nitrogen dioxide is not acidic oxide.

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    Nitrogen forms tha largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range from N_(2)O through NO,N_(2)O_(3),NO_(2),N_(2)O_(4) to N_(2)O_(5) . Following points are important regarding the study of oxides of nitrogen. (i) All oxides of nitrogen except N_(2)O_(5) are quite thermally stable (ii) The small electronegative difference between oxygen and nitrogen make N-O bond easily breakable to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (iii) Except N_(2)O_(5) , all are gases at ordinary temperaure. N_(2)O_(3) is stable only at lower temperaures (253K) (iv) Most of the oxides are acidic oxides which dissolve in water forming corresponding oxy acids. ltbr. (v) The are good examples for illustrating teh concept of resonance. Which of the following statements is correct for the oxides of nitrogen?

    Nitrogen forms tha largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range from N_(2)O through NO,N_(2)O_(3),NO_(2),N_(2)O_(4) to N_(2)O_(5) . Following points are important regarding the study of oxides of nitrogen. (i) All oxides of nitrogen except N_(2)O_(5) are quite thermally stable (ii) The small electronegative difference between oxygen and nitrogen make N-O bond easily breakable to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (iii) Except N_(2)O_(5) , all are gases at ordinary temperaure. N_(2)O_(3) is stable only at lower temperaures (253K) (iv) Most of the oxides are acidic oxides which dissolve in water forming corresponding oxy acids. ltbr. (v) The are good examples for illustrating teh concept of resonance. Identify the incorrect statement?

    Nitrogen forms tha largest number of oxides as it is capable of forming stable multiple bonds with oxygen. They range from N_(2)O through NO,N_(2)O_(3),NO_(2),N_(2)O_(4) to N_(2)O_(5) . Following points are important regarding the study of oxides of nitrogen. (i) All oxides of nitrogen except N_(2)O_(5) are quite thermally stable (ii) The small electronegative difference between oxygen and nitrogen make N-O bond easily breakable to give oxygen and hence oxides of nitrogen are said to be better oxidising agents. (iii) Except N_(2)O_(5) , all are gases at ordinary temperaure. N_(2)O_(3) is stable only at lower temperaures (253K) (iv) Most of the oxides are acidic oxides which dissolve in water forming corresponding oxy acids. ltbr. (v) The are good examples for illustrating teh concept of resonance. The gas which is acidic in nature is:

    All the oxides of nitrogen exhibits (between N and O )

    Which of the following oxides of nitrogen contains N-O-N bond ?

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