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The standard redox potentials E^@ of the...

The standard redox potentials `E^@` of the following systems are `{:("System",E^@("volts")),((i)MnO_4^(-)+BH^(+)+5e^(-)toMn^(2+)+4H_2O,1.51),((ii)Sr^(2+)toSn^(4+)+2e^(-),-0.15),((iii)Cr_2O_7^(2-)+14H^(+)+6e^(-),1.33),((iv)Ce^(3+)toCe^(4+)+e^(-),-1.61):}`
The oxidising power of the various species are related as

A

`Cr_2O_7^(2-) gt MnO_4^(-)`

B

`Ce^(4+) gt Sn^(4+)`

C

`Ce^(4+) gt MnO_4`

D

MnO_4^(-) gt Sn^(4+)`

Text Solution

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The correct Answer is:
B,C,D

`S.R.P uarr O.A uarr " " S.R.P=-S.O.P`
`E_(Ce^(+4)|Ce^(+3))^@gtE_(MnO_4^(-)|Mn^(+2))^@gtE_(Cr_2O_7^(-2)|Cr^(+3))^@gtE_(Sn^(+4)|Sn^(+2))^@`
`1. 61` `1.51` `1.33` `0.15`
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The standard reduction potential E^(@) of the following systems are:- {:(System,E^(@)("volts")),((i)MnO_(4)^(-)+8H^(+)+5e^(-)rarrMn^(2+)+4H_(2)O,1.51),((ii)Sn^(4+)+2e^(-)rarrSn^(2+)0.15,),((iii)Cr_(2)O_(7)^(2-)+14H^(+)+6e^(-)rarr2Cr^(3+)+7H_(2)O,1.33),((iv)Ce^(4+)+e^(-)rarrCe^(3+)1.61,):} The oxidising power of teh various species decreases in the order

Standard electrode potentials of few half-cell reactions are given below : {:(MnO_4^(-)+8H^(+)+5e^(-) to Mn^(2+)+ 4H_2O,,E^@=1.51V),(Cr_2O_7^(2-)+14H^(+)+6e^(-)to 2Cr^(3+)+7H_2O,,E^@=1.33V),(Fe^(3+)+e^(-)to Fe^(2+),,E^@=0.77V),(Cl_2+2e^(-) to 2Cl^(-),,E^@=1.36):} Based on the above information match the column I with column II and mark the appropriate choice.

MnO_(4)^(-) + 8H^(+) + 5e^(-) rightarrow Mn^(2+) + 4H_(2)O , E^(@) = 1.51V MnO_(2) + 4H^(+) + 2e^(-) righarrow Mn^(2+) + 2H_(2)O E^(@) = 1.23V E_(MnO_(4)^(-)|MnO_(2)

The standard electrode potential for the following reaction is +1.33 V. What is the potential at pH=2.0? Cr_(2)O_(7)^(2-)(aq,1M)+14H^(+)(aq)+6e^(-)to2Cr^(3+)(aq,1M)+7H_(2)O(l)

Two half-reactions of an electrochemical cell are given below : MnO_(4)^(-)(aq)+8H^(+)(aq)+5e^(-) toMn^(2+)(aq)+4H_(2)O(l), E^(@)=+1.51" V" Sn^(2+)(aq) to Sn^(4+)(aq)+2e^(-),E^(@)=-0.15" V"

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