Match Matrix
`{:("Column I","Column II"),((A)Zn|Zn^(2+)( C)||Zn^(2+)(2C)|Zn,(p)"Spontaneous cell reaction"),((B)H_2(P)|HCl(1N)||H_2SO_4(1N)|H_2(P),(q)"Working cell representation"),(( C)Cu|Cu^(2+)(0.01 M)||Ag^(+)(0.1M)|Ag,(r)"Concentration of cation in cathodic compartment increases upto equilibrium"),((D)Ag|AgCl|(KCl, 0.1 M)||Ag^(+)(0.01 M)|Ag,(s)"Concentration cell"),(,(t)"Concentration of"Cl^(-)"in anodic compartment decreases"):}`

Answer

A`to`p,q,s ; B`to`r,s ; C`to`p,q ; D`to`p,q,s,t

Explanation

`E_("cell")=-0.0591/2"log"C/(2C)=8.89xx10^(-3)`
Spontaneous, cell works, conc cell
`E_("cell")=-0.0591 "log"1/0.5 =- 0.0591`
Non spontaneous cell will not work conc cell
`E_("cell")=-0.0591/2"log"0.01/0.1^2-0.74+0.8=0.06`
Spontaneous cell works
`E_("cell")=-0.0591/1"log"(Cl^-)/(K_(sp))-0.0591/1"log"1/([Ag^+])`
`=0.0591/2"log"(0.1xx0.1)/(K_(sp(AgCl))=+ve`
Spontaneous cell works conc cell
For anode
`Ag(s)+Cl^(-)(aq)toAgCl(s)+e^-`