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A compound has the formula C2HCl2Br. The...

A compound has the formula `C_2HCl_2Br.` The number of non - identical structures that are possible is

A

one

B

two

C

three

D

four

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of non-identical structures for the compound with the formula \( C_2HCl_2Br \), we will follow these steps: ### Step 1: Calculate the Degree of Unsaturation The degree of unsaturation (DU) can be calculated using the formula: \[ DU = C - \frac{H + X}{2} + 1 \] where: - \( C \) = number of carbon atoms - \( H \) = number of hydrogen atoms - \( X \) = number of halogen atoms (Cl, Br) For \( C_2HCl_2Br \): - \( C = 2 \) - \( H = 2 \) - \( X = 2 \) (2 Cl) Substituting the values: \[ DU = 2 - \frac{2 + 2}{2} + 1 = 2 - 2 + 1 = 1 \] ### Step 2: Interpret the Degree of Unsaturation A degree of unsaturation of 1 indicates that there is either a double bond or a ring in the structure. ### Step 3: Construct Possible Structures 1. **First Structure**: A double bond between the two carbon atoms with both chlorine atoms on one carbon. - Structure: \( C=C(Cl)(Cl) \) with \( H \) and \( Br \) on the other carbon. 2. **Second Structure**: A double bond with one chlorine on each carbon. - Structure: \( C=C(Cl)(H) \) with \( Cl \) on one carbon and \( Br \) on the other carbon. 3. **Third Structure**: A double bond with the two chlorine atoms on opposite sides (trans configuration). - Structure: \( C=C(Cl)(Br) \) with \( H \) on one carbon and \( Cl \) on the other carbon. ### Step 4: Identify Non-identical Structures - The first structure has both chlorines on the same carbon, making it unique. - The second structure has one chlorine on each carbon, which is also unique. - The third structure has the chlorines on opposite sides, making it a distinct geometric isomer. ### Conclusion The total number of non-identical structures possible for the compound \( C_2HCl_2Br \) is **3**.
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