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Anisole on reaction with HI gives phenol...

Anisole on reaction with HI gives phenol and `CH_(3)-I` as the main products and not iodobenzene and `CH_(3)OH.` Assign reasons.

A

phenol and methyl iodide

B

iodobenzene and methanol

C

iodobenzene and methyl iodide

D

phenol and methanol

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The correct Answer is:
A
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(CH_(3))_(3)C-OCH_(3) on reaction with HI gives (CH_(3))_(3)C-I and CH_(3)-OH as the main products and not (CH_(3))_(3)C-OH and CH_(3)-I . Explain.

(CH_(3))_(3)C-Br on reaction with sodium methoxide (Na^("+)O^(-)CH_(3)) gives as the main product and not an ether. Assign reason.

Phenyl methyl ether (on anisole) reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol. Justify .

on reaction with CH_(3)OH in presence of H^(+) gives :

Cleavage of anisole with HI at 373 K gives phenol and CH_(3)I Reason : Due to resonance, O-C_(6)H_(5) bond is stronger than O-CH_(3) bond.

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