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CH3-underset(Br)underset(|)(CH)-underset...

`CH_3-underset(Br)underset(|)(CH)-underset(Br)underset(|)(CH_2)underset(alc.)overset(KOH)rarrCH_3-CH=underset(Br)underset(|)(CH)overset("Reagent")rarrCH_3C-=CH` The reagent is

A

sodium

B

KOH in etanol

C

sodamide

D

zinc dust in ethanol

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The correct Answer is:
To solve the given question, we need to identify the reagent that can convert the compound 1-bromo-2-propene (CH3-CH=CH-Br) into propene (CH3-C≡C-H). ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting compound is 1-bromo-2-propene (CH3-CH=CH-Br). This compound has a vinylic bromine (Br) attached to a carbon that is part of a double bond. 2. **Understand the Reaction Type**: The reaction involves the removal of HBr from the starting material to form an alkyne. This process is known as dehydrohalogenation. 3. **Determine the Required Reagent**: To achieve the conversion from a vinylic halide to an alkyne, we need a strong base that can effectively remove the hydrogen atom adjacent to the vinylic bromine. 4. **Evaluate the Options**: - **Sodium (Na)**: Sodium is not a suitable reagent here as it does not effectively remove the vinylic bromine. - **KOH in Ethanol**: While KOH is a strong base, it is not strong enough to remove the vinylic hydrogen and facilitate the formation of an alkyne. - **Sodamide (NaNH2)**: This is a strong base and can effectively remove the hydrogen atom adjacent to the bromine, allowing for the formation of the alkyne. - **Zinc Dust in Ethanol**: This is not applicable as it typically reacts with vicinal dihalides and would not lead to the formation of an alkyne from a vinylic halide. 5. **Conclusion**: The only reagent that can effectively convert 1-bromo-2-propene to propene is **Sodamide (NaNH2)**. ### Final Answer: The reagent is **Sodamide (NaNH2)**.
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CH_(3)-underset(CH_(3))underset(|)(C)=CH-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(3)

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CH_(3)-CH_(2)-underset(Br)underset(|)(CH)-CH_(3)underset(Delta)overset("alc.KOH")rarrX (Major)

Consider the following reactions: underset(Br)underset(|)(CH_(3))-underset(Br)underset(|)(CH_(2)) underset(H_(2)O,Delta)overset(NaOH)toA overset(NaH)toB,B+underset(Br)underset(|)(CH_(2))-underset(Br)underset(|)(CH_(2))toC The major product formed is:

The IUPAC name of CH_(3)-underset(OH)underset(|)(CH)-underset(CH_(3))underset(|)(CH)-underset(OH)underset(|)(CH)-overset(" "CH_(3))overset(|)underset(" " CH_(3))underset(|)(C)-CH_(3) is:

The IUPAC name of CH_(3)-underset(CI)underset(|)(CH)-underset(Br)underset(|)(CH)-underset(OH)underset(|)(CH)-CH_(3) is:

The IUPAC name of CH_(3)-CH_(2)-underset(CI)underset(|)(CH)-underset(CH_(3))underset(|)(CH)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-CH_(3) is :

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