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Anhydrous aluminium chloride (Al(2)Cl(6)...

Anhydrous aluminium chloride `(Al_(2)Cl_(6))` is covalent compound and soluble in water giving:

A

`Al^(3+) and Cl^(-)` ions

B

`[Al(H_2O)_6]^(3+) and Cl^(-)` ions

C

`[AlCl_2(H_2O)_4]^+ and [AlCl_4(H_2O)_2]^(-)` ions

D

none of the above

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The correct Answer is:
C
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Calculate the enthalpy of formation of anhydrous aluminium chloride, Al_(2)Cl_(6) from the following data : (i) 2Al(s) + 6HCl (aq) to Al_(2)Cl_(6) (aq) + 3H_(2)(g), Delta_(r)H^(@) = -1004.0 kJ (ii) H_(2)(g) + Cl_(2)(aq) to 2HCl(g) , Delta_(r)H^(@) = -183.9 kJ , Delta_(r)H^(@) = -183.9 kJ (iii) HCl(g) + aq to HCl(aq), Delta_(r)H^(@) = -73.2 kJ Al_(2)Cl_(6)(s) + aq to Al_(2) Cl_(2)(aq) , Delta_(r)H^(@) = -643.0 kJ

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