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Identify the final product (Z) in the fo...

Identify the final product (Z) in the following sequence of reaction.
`C_6H_(13)COCloverset("H_2,Pd//BaSO_4)rarr(X)overset(C_6H_(13)NH_2)rarr (Y)overset(H_2//Ni)rarr(Z)`

A

`C_6H_(13)CH_2NHC_6H_(13)`

B

`C_(12)H_(25)CH_2NH_2`

C

`C_6H_(13)-underset(C_6H_14)underset(|)(CH)-NH_2`

D

`(C_6H_(13))_2CH_3N`

Text Solution

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The correct Answer is:
To identify the final product (Z) in the given sequence of reactions, we will follow the steps outlined in the reaction sequence. ### Step-by-Step Solution: 1. **Identify the starting compound (C6H13COCl)**: - The compound is an acyl chloride (specifically, hexanoyl chloride) with the formula C6H13COCl. 2. **First Reaction: Rosenmund Reduction**: - The acyl chloride (C6H13COCl) is treated with hydrogen gas (H2) in the presence of palladium on barium sulfate (Pd/BaSO4). - This reaction is known as the Rosenmund reduction, which converts acyl chlorides into aldehydes. - The product (X) of this reaction will be C6H13CHO (hexanal). 3. **Second Reaction: Reaction with Amine (C6H13NH2)**: - The aldehyde (C6H13CHO) is then reacted with a primary amine (C6H13NH2). - The reaction between an aldehyde and a primary amine leads to the formation of an imine (C6H13CH=NH). - The product (Y) of this reaction will be C6H13CH=NH. 4. **Third Reaction: Hydrogenation**: - The imine (C6H13CH=NH) is subjected to hydrogenation in the presence of nickel (Ni) as a catalyst. - Hydrogenation of an imine will convert it into an amine by adding hydrogen across the double bond. - The final product (Z) will be C6H13CH2NH2 (hexylamine). ### Final Product: - The final product (Z) is C6H13CH2NH2, which is hexylamine. ### Summary of Products: - X = C6H13CHO (hexanal) - Y = C6H13CH=NH (imine) - Z = C6H13CH2NH2 (hexylamine)
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