Home
Class 12
CHEMISTRY
In the given reaction [C6H5-CH2-CH2-over...

In the given reaction `[C_6H_5-CH_2-CH_2-overset(o+)(N)(CH_3)_2-CH_2-CH_3]overset(Theta)(OH)overset(Delta)rarr` (X) as major product will be

A

`C_6H_5-CH=CH_2`

B

`CH_2=CH_2`

C

`C_6H_5-CH=CH-CH_3`

D

`CH_3-CH=CH-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, let's analyze the reaction and apply the concepts of elimination reactions, particularly Hofmann elimination. ### Step 1: Understand the Structure The compound provided in the reaction is a tertiary amine with a phenyl group. The structure can be drawn as follows: - The phenyl group (C6H5) is attached to a CH2 group. - This CH2 group is connected to another CH2 group, which is then connected to a nitrogen atom (N) that has two methyl groups (CH3) attached to it. - The nitrogen is positively charged, indicating that it is a quaternary ammonium ion. ### Step 2: Identify the Type of Reaction The reaction involves the use of OH⁻ (hydroxide ion) and heating, which suggests that we are dealing with an elimination reaction. Given that we have a quaternary ammonium ion, this points towards Hofmann elimination. ### Step 3: Apply Hofmann Elimination In Hofmann elimination, the reaction typically leads to the formation of the least stable alkene (the less substituted alkene). 1. The hydroxide ion (OH⁻) can abstract a hydrogen atom from the carbon adjacent to the nitrogen. 2. There are two possible hydrogen atoms that can be abstracted: - One from the CH2 group adjacent to the nitrogen. - The other from the CH2 group that is further away from the nitrogen. ### Step 4: Determine the Major Product - If the hydrogen from the CH2 group adjacent to the nitrogen is abstracted, the product will be ethylene (CH2=CH2). - If the hydrogen from the CH2 group further away from the nitrogen is abstracted, the product will be styrene (C6H5-CH=CH2), which is more substituted and therefore more stable. According to Hofmann elimination, the major product will be the less substituted alkene, which in this case is ethylene. ### Step 5: Conclusion The major product (X) formed in this reaction is ethylene (CH2=CH2). ### Final Answer The major product (X) will be ethylene (CH2=CH2). ---
Promotional Banner

Topper's Solved these Questions

  • NTA NEET SET 88

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos
  • NTA NEET SET 90

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos

Similar Questions

Explore conceptually related problems

In the given reaction, OHC-(CH_(2))_(3)-overset(O)overset(||)C-CH_(3)overset(overset(Theta)(O)H//Delta)rarr (X)' the major product 'X' will be

In the given reaction CH_3-CH_2-CH_2-O-CH_2-CH_3 overset("Conc.Hl)rarr(X)+(Y)

In the given reaction, CH_(3)-underset(CH_3)underset(|)(CH)-overset(O)overset(||)(C )-CH_2-CH_3 overset(CF_3CO_3H)(rarr)(X) as main product, 'X' will be

In the given reaction CH_3-CH_2-overset(Br)overset(|)(CH)-CH=CH_2overset("Alc.KOH//Delta)rarr(X) X will be

In the given reaction CH_3-underset(CH_3)underset(|)overset(CH_3)overset(|)C-CH_2-Broverset(Delta)rarr[X] [X] will be

In the given reaction CH_3-overset(Br)overset(|)(C )H-CH_2-COOH overset(NaOH)(rarr)(X) . 'X' will be

In the given reaction overset(Br)overset(|)(CH_2)-CH=CH_2overset(NaNH_2//Delta)rarr(X) X will be

The given reaction CH_3-CH_2-CH_3 overset(Br_2//hv)(rarr)CH_3-overset(Br)overset(|)(C )H-CH_3+HBr is an example of

In the given reaction C_6H_5-CH_2-CH_3overset(NBS)rarr(X)overset(Alc.KOH//Delta)rarr(Y) In the given reaction X and Y respectively are

NTA MOCK TESTS-NTA NEET SET 89-CHEMISTRY
  1. Ph-CHO+Ph-CHOoverset(Na(2)[Fe(CO)(4)])rarrPh-overset(O)overset("||")C-...

    Text Solution

    |

  2. Depletion of ozone layer causes

    Text Solution

    |

  3. Among the carbonates of alkali metals which one has highest thermal st...

    Text Solution

    |

  4. The efficiency of a hypothetical cell is about 84% which involves the ...

    Text Solution

    |

  5. An acid solution of pH=6 is diluted 1000 times, the pH of the final so...

    Text Solution

    |

  6. The number of aromatic structures possible for the molecular formula C...

    Text Solution

    |

  7. Which of the following alkenes is the most stable ?

    Text Solution

    |

  8. During micelle formation :

    Text Solution

    |

  9. The graph between log t(1//2) and log a at a given temperature is ...

    Text Solution

    |

  10. Consider the following reaction CH3-underset((A))(CH2)-O-H+CH3-underse...

    Text Solution

    |

  11. In the given reaction [C6H5-CH2-CH2-overset(o+)(N)(CH3)2-CH2-CH3]overs...

    Text Solution

    |

  12. Select correct statement for Cr. 6NH3.Cl3 and Cr.5NH2.Cl3

    Text Solution

    |

  13. In the reaction CH(3)-C-=C-Hoverset(CH(3)MgBr)toCH(4)+(A)underset((i...

    Text Solution

    |

  14. In the hober's process of ammonia manufacture, N(2)(g)+3H(2)(g) rarr...

    Text Solution

    |

  15. The period number and group number of "Tantalum" (Z=73) are respective...

    Text Solution

    |

  16. Which of the following will not form Grignard reagent with Mg/dry ethe...

    Text Solution

    |

  17. A certain sample of cuprous sulphide is found to have composition Cu(1...

    Text Solution

    |

  18. The product of the reaction CHO+(C6H5-CHCO)2Ooverset(C6H5-CH2COONa//D...

    Text Solution

    |

  19. Which one of the following behaves both as a nucleophile and an electr...

    Text Solution

    |

  20. Here the compound Y is

    Text Solution

    |