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In the given reaction C6H5-CH=CH-CH3+HCl...

In the given reaction `C_6H_5-CH=CH-CH_3+HCl rarr[X]` [X] will be

A

`C_6H_5-overset(Cl) overset(|)(CH)-CH_2-CH_3`

B

`C_6H_5-CH_2-overset(Cl)overset(|)(CH)-CH_3`

C

`Cl-C_6H_4-CH=CH-CH_3`

D

`C_6H_5-CH=CH-CH_2Cl`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product [X] formed from the reaction of the compound \( C_6H_5-CH=CH-CH_3 \) with HCl, we can follow these steps: ### Step 1: Identify the Reaction Type The reaction involves an alkene (the double bond between carbon atoms) reacting with HCl. This is an electrophilic addition reaction. ### Step 2: Protonation of the Alkene In the presence of HCl, the double bond will react with HCl. The first step is the protonation of the alkene. The double bond can either attack the hydrogen ion (H⁺) from HCl at carbon 1 or carbon 2. 1. **If H⁺ adds to carbon 1**: - The structure becomes: \[ C_6H_5-CH^+-CH_2-CH_3 \] - This forms a carbocation at carbon 1. 2. **If H⁺ adds to carbon 2**: - The structure becomes: \[ C_6H_5-CH_2-CH^+-CH_3 \] - This forms a carbocation at carbon 2. ### Step 3: Stability of Carbocations Next, we need to evaluate the stability of the two possible carbocations formed: - **Carbocation at Carbon 1**: - This carbocation is stabilized by resonance with the benzene ring. The positive charge can be delocalized over the aromatic system, making it more stable. - **Carbocation at Carbon 2**: - This carbocation is less stable because it is only stabilized by hyperconjugation from the adjacent alkyl group (methyl group). The positive charge is localized and not delocalized. ### Step 4: Nucleophilic Attack Since the carbocation at carbon 1 is more stable, it is the favored intermediate. The next step is the attack of the chloride ion (Cl⁻) on the carbocation: - The chloride ion will attack the more stable carbocation (at carbon 1), resulting in the formation of the product. ### Step 5: Final Product The final product [X] will be: \[ C_6H_5-CH(Cl)-CH_2-CH_3 \] This can be represented as: \[ C_6H_5-CHCl-CH_2-CH_3 \] ### Conclusion Thus, the product [X] formed from the reaction of \( C_6H_5-CH=CH-CH_3 \) with HCl is \( C_6H_5-CHCl-CH_2-CH_3 \). ---
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