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Which of the following carbonyl compound...

Which of the following carbonyl compounds will give recemisation reaction in the presence of acid base ?

A

`CH_3-overset(O)overset(||)C-CH_2-CH_3`

B

`CH_3-overset(O)overset(||)C-underset(CH_3)underset(|)overset(H)overset(|)C-C_2H_5`

C

`CH_3-overset(O)overset(||)C-underset(CH_3)underset(|)overset(CH_3)overset(|)C-C_2H_5`

D

`CH_3-overset(O)overset(||)C-underset(CH_3)underset(|)overset(CH_3)overset(|)C-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which carbonyl compound will undergo racemization in the presence of acid-base conditions, we need to follow these steps: ### Step 1: Identify the Criteria for Racemization Racemization occurs when a compound can convert between its enantiomers, leading to a mixture of both forms. For a carbonyl compound to undergo racemization, it must meet two criteria: 1. It must have at least one alpha hydrogen. 2. It must have a chiral center. ### Step 2: Analyze the Given Options We will analyze each of the four options provided to identify if they meet the criteria for racemization. - **Option 1:** Check for alpha hydrogens and chiral centers. - **Option 2:** Check for alpha hydrogens and chiral centers. - **Option 3:** Check for alpha hydrogens and chiral centers. - **Option 4:** Check for alpha hydrogens and chiral centers. ### Step 3: Evaluate Each Option 1. **Option 1:** - Contains alpha hydrogens but lacks a chiral center. - **Conclusion:** No racemization. 2. **Option 2:** - Contains alpha hydrogens and has a chiral center. - **Conclusion:** Possible racemization. 3. **Option 3:** - Lacks alpha hydrogens and lacks a chiral center. - **Conclusion:** No racemization. 4. **Option 4:** - Contains alpha hydrogens but lacks a chiral center. - **Conclusion:** No racemization. ### Step 4: Identify the Correct Option From the analysis, only **Option 2** contains both alpha hydrogens and a chiral center, making it the only compound that can undergo racemization in the presence of acid-base conditions. ### Final Answer The correct answer is **Option 2**. ---
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