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CH3-C-=Noverset(H2"O"//Delta)rarr(A)over...

`CH_3-C-=Noverset(H_2"O"//Delta)rarr(A)overset(H_2"O"//H^+)rarr(B)(A) and (B)` respectively are

A

`CH_3-overset(O)overset(||)C-NH_2and CH_3COOH`

B

`CH_3COONH_4and CH_3COOH`

C

`CH_3CONH_2 and CH_3COONH_4`

D

`CH_3-CH=NH and CH_3COOH`

Text Solution

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The correct Answer is:
To solve the question, we need to analyze the reactions of CH₃CN (acetonitrile) with water (H₂O) under different conditions. ### Step-by-Step Solution: 1. **Identify the Reactant:** The starting compound is CH₃CN, which is acetonitrile. 2. **Partial Hydrolysis of CH₃CN:** When CH₃CN reacts with water (H₂O) under mild conditions (without strong acid or base), it undergoes partial hydrolysis. This means it is converted into an amide. - The reaction can be represented as: \[ \text{CH}_3\text{CN} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{C(O)NH}_2 \quad \text{(Amide)} \] - The product formed (A) is **acetamide (CH₃C(O)NH₂)**. 3. **Complete Hydrolysis of Acetamide:** Next, when acetamide (A) undergoes hydrolysis in the presence of an acid (H⁺), it is completely hydrolyzed to form a carboxylic acid and ammonia. - The reaction can be represented as: \[ \text{CH}_3\text{C(O)NH}_2 + \text{H}_2\text{O} \xrightarrow{\text{H}^+} \text{CH}_3\text{COOH} + \text{NH}_3 \] - The product formed (B) is **acetic acid (CH₃COOH)**. 4. **Final Products:** - Therefore, the structures of A and B are: - A: Acetamide (CH₃C(O)NH₂) - B: Acetic Acid (CH₃COOH) ### Conclusion: The final answer is: - (A) Acetamide (CH₃C(O)NH₂) - (B) Acetic Acid (CH₃COOH)
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