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In the given reaction CH3-CH2-overset(Br...

In the given reaction `CH_3-CH_2-overset(Br)overset(|)(CH)-CH=CH_2overset("Alc.KOH//Delta)rarr(X)` X will be

A

`CH_3-CH_2-CH=C=CH_2`

B

`CH_2=CH-CH_2-CH=CH_2`

C

`CH_3-CH=CH-CH=CH_2`

D

`CH_3-CH_2-CH_2-C-=CH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction `CH_3-CH_2-overset(Br)overset(|)(CH)-CH=CH_2overset("Alc.KOH//Delta)rarr(X)`, we will follow these steps: ### Step 1: Identify the Reactants The reactant is a compound with a bromine (Br) leaving group attached to a carbon chain that also has a double bond. The structure can be represented as: ``` Br | CH3-CH2-C-CH=CH2 ``` Here, the bromine is attached to the carbon that is also connected to the double bond. ### Step 2: Understand the Reaction Conditions The reaction is carried out in the presence of alcoholic KOH and heat (Δ). Alcoholic KOH is a strong base that promotes elimination reactions, specifically dehydrohalogenation, which involves the removal of HX (where X is Br in this case). ### Step 3: Mechanism of the Reaction In the dehydrohalogenation reaction: 1. The base (KOH) abstracts a proton (H) from a carbon adjacent to the carbon bonded to Br. 2. The bromine (Br) leaves, resulting in the formation of a double bond between the two carbons. ### Step 4: Determine the Possible Products The elimination can occur in two ways: - The proton can be abstracted from the carbon adjacent to the carbon with Br. - The proton can be abstracted from the carbon on the opposite side of the double bond. This leads to the formation of an alkene. The product will be a more stable alkene, which is typically the more substituted alkene (Zaitsev's rule). ### Step 5: Identify the Final Product After considering the stability of the possible products, we find that the more stable product is a conjugated diene. The final structure will have a double bond between the two carbons that were involved in the elimination, and the resulting product will be: ``` CH2=CH-CH=CH2 ``` This represents a conjugated diene, which is more stable due to the overlap of p-orbitals. ### Conclusion The product X formed from the reaction is: ``` X = CH2=CH-CH=CH2 (1,3-butadiene) ```
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