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In the given reaction C6H5-CH2-CH3overse...

In the given reaction `C_6H_5-CH_2-CH_3overset(NBS)rarr(X)overset(Alc.KOH//Delta)rarr(Y)` In the given reaction X and Y respectively are

A

`C_6H_5-CHBr-CH_3 and C_6H_5-C-=CH`

B

`C_6H_5-CBr_2-CH_3 and C_6H_5-C-=CH`

C

`C_6H_5-CBr_2-CH_3 and C_6H_5-CBr-=CH_2`

D

`C_6H_5-CHBr-CH_3and C_6H_5-CH=CH_2`

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AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction involving N-bromosuccinimide (NBS) and alcoholic KOH, we will break down the steps involved in the reaction to identify the compounds X and Y. ### Step-by-Step Solution: **Step 1: Identify the starting compound** - The starting compound is `C6H5-CH2-CH3`, which is ethylbenzene. **Step 2: Reaction with N-bromosuccinimide (NBS)** - N-bromosuccinimide is used to brominate the benzylic position of the ethylbenzene. This reaction proceeds via a free radical mechanism. - The hydrogen atom from the benzylic position (the `CH2` group) is abstracted by a bromine radical (Br•), generating a benzylic radical. **Step 3: Formation of the benzylic radical** - The structure of the benzylic radical formed is `C6H5-CH•-CH3`. This radical is stabilized by resonance due to the adjacent aromatic ring, which allows for multiple resonance structures. **Step 4: Bromination of the benzylic radical** - The benzylic radical then reacts with another bromine atom from NBS to form the benzylic bromide, `C6H5-CHBr-CH3`. This compound is our product X. **Step 5: Reaction with alcoholic KOH** - The next step involves treating the benzylic bromide with alcoholic KOH. Alcoholic KOH acts as a strong base and facilitates dehydrohalogenation. - The base abstracts a hydrogen atom from the beta position (the `CH3` group), leading to the elimination of HBr and the formation of a double bond. **Step 6: Formation of the alkene** - The product formed after dehydrohalogenation is `C6H5-CH=CH2`. This compound is our product Y, which is an alkene. ### Final Products: - Therefore, the compounds X and Y are: - **X**: `C6H5-CHBr-CH3` (benzylic bromide) - **Y**: `C6H5-CH=CH2` (alkene) ### Conclusion: The answer to the question is: - **X**: `C6H5-CHBr-CH3` - **Y**: `C6H5-CH=CH2`
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