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The equilibrium constant for the reactio...

The equilibrium constant for the reaction `H_(2)O(g)+CO(g)hArrH_(2)(g)+CO_(2)(g)` is 0.44 at 1660 K. The equilibrium constant for the reaction
`2H_(2)(g)+2CO_(2)(g)hArr 2CO(g)+2H_(2)O(g)`
at 1660 K is equal to

A

0.44

B

0.88

C

5.16

D

126

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The correct Answer is:
To solve the problem, we need to find the equilibrium constant for the reaction: \[ 2H_2(g) + 2CO_2(g) \rightleftharpoons 2CO(g) + 2H_2O(g) \] given that the equilibrium constant for the reaction: \[ H_2O(g) + CO(g) \rightleftharpoons H_2(g) + CO_2(g) \] is \( K_1 = 0.44 \) at 1660 K. ### Step-by-step Solution: 1. **Reverse the Original Reaction**: The equilibrium constant for the reverse reaction is the reciprocal of the original equilibrium constant. Therefore, for the reaction: \[ H_2(g) + CO_2(g) \rightleftharpoons H_2O(g) + CO(g) \] The equilibrium constant \( K_2 \) is given by: \[ K_2 = \frac{1}{K_1} = \frac{1}{0.44} \] 2. **Calculate \( K_2 \)**: Now, we can calculate \( K_2 \): \[ K_2 = \frac{1}{0.44} \approx 2.27 \] 3. **Multiply the Reaction by 2**: We need to find the equilibrium constant for the reaction: \[ 2H_2(g) + 2CO_2(g) \rightleftharpoons 2CO(g) + 2H_2O(g) \] When a balanced equation is multiplied by a factor, the equilibrium constant is raised to the power of that factor. Therefore, we have: \[ K_3 = K_2^2 \] 4. **Calculate \( K_3 \)**: Now, substituting \( K_2 \) into the equation: \[ K_3 = (2.27)^2 \] Calculating this gives: \[ K_3 \approx 5.15 \] 5. **Final Answer**: Thus, the equilibrium constant for the reaction \( 2H_2(g) + 2CO_2(g) \rightleftharpoons 2CO(g) + 2H_2O(g) \) at 1660 K is approximately: \[ K_3 \approx 5.15 \] ### Summary: The equilibrium constant for the reaction \( 2H_2(g) + 2CO_2(g) \rightleftharpoons 2CO(g) + 2H_2O(g) \) at 1660 K is approximately 5.15.
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