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In the sequence of reactions C(6)H(5)B...

In the sequence of reactions
`C_(6)H_(5)Broverset(Mg)underset("ether")rarr (X) overset((i)CO_(2))underset((iii)H_(3)O^(+))rarr(Y)` the product (Y) is

A

biphenyl

B

m - bromobenzoic acid

C

benzoic acid

D

benzyl alcohol

Text Solution

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The correct Answer is:
To solve the problem, we will go through the sequence of reactions step by step. ### Step 1: Formation of Grignard Reagent The first step involves the reaction of phenyl bromide (C₆H₅Br) with magnesium (Mg) in the presence of ether. This reaction produces a Grignard reagent. **Reaction:** \[ C₆H₅Br + Mg \xrightarrow{\text{ether}} C₆H₅MgBr \] Here, C₆H₅MgBr is the Grignard reagent (denoted as X). ### Step 2: Reaction with Carbon Dioxide Next, the Grignard reagent (C₆H₅MgBr) reacts with carbon dioxide (CO₂). The nucleophilic carbon of the Grignard reagent attacks the electrophilic carbon of CO₂. **Reaction:** \[ C₆H₅MgBr + CO₂ \rightarrow C₆H₅C(=O)O^{-}MgBr^{+} \] This intermediate product is a carboxylate ion (C₆H₅C(=O)O⁻) with magnesium bromide (MgBr⁺). ### Step 3: Hydrolysis The final step involves the hydrolysis of the carboxylate ion in the presence of an acid (H₃O⁺). This hydrolysis converts the carboxylate ion into a carboxylic acid. **Reaction:** \[ C₆H₅C(=O)O^{-}MgBr^{+} + H₃O^{+} \rightarrow C₆H₅C(=O)OH + MgBr^{+} + H₂O \] The product of this reaction is benzoic acid (C₆H₅C(=O)OH), denoted as Y. ### Final Answer The product (Y) is **benzoic acid (C₆H₅COOH)**. ---
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