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Ester containing alpha- hydrogens underg...

Ester containing `alpha-` hydrogens undergo self condensation in presence of a strong base such as sodium ethoxide to form `beta-` ketoesters. This reaction is called

A

Aldol condensation

B

Claisen condensation

C

Diekmann condensation

D

Crossed - Claisen condensation

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To solve the question regarding the reaction of esters containing alpha-hydrogens undergoing self-condensation in the presence of a strong base, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reactants**: - We start with an ester that contains alpha-hydrogens. An example of such an ester could be ethyl acetate (CH3COOCH2CH3). 2. **Role of Strong Base**: - A strong base, such as sodium ethoxide (NaOEt), is used in this reaction. The strong base will abstract the alpha-hydrogen from the ester, creating an enolate ion. 3. **Formation of Enolate Ion**: - The abstraction of the alpha-hydrogen leads to the formation of an enolate ion. This enolate ion is a nucleophile and is crucial for the next step of the reaction. 4. **Self-Condensation**: - The enolate ion formed can then attack another molecule of the ester at the carbonyl carbon (the electrophilic site). This results in the formation of a beta-ketoester. 5. **Final Product**: - The product of this self-condensation reaction is a beta-ketoester. For example, if we started with ethyl acetate, the product would be 3-oxobutanoate. 6. **Naming the Reaction**: - The reaction that occurs is known as the **Claisen condensation**. This term specifically refers to the self-condensation of esters in the presence of a strong base to form beta-ketoesters. ### Final Answer: The reaction is called **Claisen condensation**.
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