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The first orbital of H is represented by...

The first orbital of H is represented by: `psi=(1)/(sqrtr)((1)/(a_(0)))^(3//2)e^(-r//a_(0))`, where `a_(0)` is Bohr's radius. The probability of finding the electron at a distance r, from the nucleus in the region dV is :

A

`psi^(2)dr`

B

`int psi^(2)4pir^(2)dv`

C

`psi^(2)4pir^(2)dr`

D

`int psidv`

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The correct Answer is:
To solve the problem of finding the probability of locating the electron at a distance \( r \) from the nucleus in the hydrogen atom, we can follow these steps: ### Step 1: Understand the Wave Function The wave function for the first orbital of hydrogen is given as: \[ \psi = \frac{1}{\sqrt{r}} \left(\frac{1}{a_0}\right)^{3/2} e^{-r/a_0} \] where \( a_0 \) is the Bohr radius. ### Step 2: Calculate the Probability Density The probability density \( P \) is given by the square of the wave function: \[ P = |\psi|^2 = \psi \cdot \psi^* = \left(\frac{1}{\sqrt{r}} \left(\frac{1}{a_0}\right)^{3/2} e^{-r/a_0}\right)^2 \] This simplifies to: \[ P = \frac{1}{r} \left(\frac{1}{a_0}\right)^3 e^{-2r/a_0} \] ### Step 3: Determine the Volume Element In spherical coordinates, the volume element \( dV \) at a distance \( r \) is given by: \[ dV = 4\pi r^2 dr \] ### Step 4: Calculate the Probability of Finding the Electron The probability \( dP \) of finding the electron in the shell between \( r \) and \( r + dr \) is given by: \[ dP = P \cdot dV = \left(\frac{1}{r} \left(\frac{1}{a_0}\right)^3 e^{-2r/a_0}\right) \cdot (4\pi r^2 dr) \] This simplifies to: \[ dP = 4\pi \left(\frac{1}{a_0}\right)^3 e^{-2r/a_0} r dr \] ### Step 5: Final Expression Thus, the probability of finding the electron at a distance \( r \) from the nucleus in the region \( dV \) is: \[ dP = \frac{4\pi}{a_0^3} r e^{-2r/a_0} dr \]
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