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In the given reaction sequence C(6)H(5...

In the given reaction sequence
`C_(6)H_(5)CHO+CH_(3)-NO_(2)overset((i)NaOH(ii)Delta)rarr[X]`
[X] will be

A

`C_(6)H_(5)-CHOH-CH_(2)-CHO`

B

`C_(6)H_(5)CH_(2)OH`

C

`C_(6)H_(5)-COOH`

D

`C_(6)H_(5)-CH=CH-NO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction sequence involving benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂), we will follow these steps: ### Step 1: Identify the Reactants The reactants in the reaction are benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂). ### Step 2: Understand the Role of Nitromethane Nitromethane has a hydrogen atom that is acidic due to the presence of the nitro group. This means that it can lose a proton (H⁺) to form a nitromethane anion (CH₂NO₂⁻). ### Step 3: Formation of the Nucleophile When we add NaOH to the reaction mixture, it will deprotonate nitromethane, generating the nitromethane anion (CH₂NO₂⁻). This anion acts as a nucleophile. ### Step 4: Nucleophilic Attack on Benzaldehyde The nucleophile (CH₂NO₂⁻) will attack the electrophilic carbon of the carbonyl group in benzaldehyde (C₆H₅CHO). This results in the formation of a tetrahedral intermediate. ### Step 5: Proton Transfer In the tetrahedral intermediate, the oxygen of the carbonyl group will take a proton (H⁺) from water or the surrounding medium, leading to the formation of an alcohol functional group. The resulting compound will have the structure: C₆H₅C(OH)(CH₂NO₂). ### Step 6: Elimination Reaction Upon heating (Δ), a beta elimination reaction occurs. The hydroxyl group (OH) and a hydrogen atom from the adjacent carbon (the one attached to the nitro group) will be eliminated as water (H₂O). This results in the formation of an alkene. ### Step 7: Final Product The final product after elimination will be C₆H₅CH=CHNO₂, which is an alkene with a nitro group. ### Conclusion Thus, the compound [X] formed in the reaction sequence is C₆H₅CH=CHNO₂. ### Final Answer [X] = C₆H₅CH=CHNO₂ ---
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